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440159
3-(Trimethoxysilyl)propyl methacrylate
98%
Synonym(s):
Silane A174, [3-(Methacryloyloxy)propyl]trimethoxysilane
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| Size/SKU | Availability | Price |
|---|---|---|
100 mL | Check Cart for Availability | $64.30 |
500 mL | Check Cart for Availability | $84.80 |
About This Item
Linear Formula:
H2C=C(CH3)CO2(CH2)3Si(OCH3)3
CAS Number:
Molecular Weight:
248.35
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
219-785-8
Beilstein/REAXYS Number:
1952435
MDL number:
$64.30
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Quality Segment
assay
98%
form
liquid
impurities
1% methyl alcohol from hydrolysis
refractive index
n20/D 1.431 (lit.)
bp
190 °C (lit.)
density
1.045 g/mL at 25 °C (lit.)
SMILES string
CO[Si](CCCOC(=O)C(C)=C)(OC)OC
InChI
1S/C10H20O5Si/c1-9(2)10(11)15-7-6-8-16(12-3,13-4)14-5/h1,6-8H2,2-5H3
InChI key
XDLMVUHYZWKMMD-UHFFFAOYSA-N
General description
3-(Trimethoxysilyl)propyl methacrylate (TMSPMA) is widely used as a monomer and as a coupling agent in polymerization reactions. It copolymerized with other monomers, such as styrene or acrylates, to produce polymer films with improved mechanical properties and adhesion to various substrates. It also improves the stability of the polymer to UV radiation. Additionally, TMSPMA is also used as a crosslinking agent in polymer gels, as it reacts with other functional groups, such as hydroxyl or carboxyl groups, to form stable covalent bonds that improve the mechanical properties of the polymer. Furthermore, TMSPMA has also been used in various fields which include, lithium-ion batteries, engineering applications dental restorative materials, and various other biomedical applications.
Application
3-(Trimethoxysilyl)propyl methacrylate (TMSPMA) can be used as:
- A linker molecule to synthesize a scaffold based on a TMSPMA-polyhedral oligomeric silsesquioxane (POSS) hybrid for potential tissue engineering applications.
- A coupling agent in the preparation of visible-light-curable urethane-modified epoxy acrylate/SiO2 composites to improve the adhesion between the filler, SiO2 nanoparticles, and the resin matrix. These composites are further applicable as dental restorative materials.
- A monomer to synthesize a polymer electrolyte material for use in lithium-ion batteries.
- A silane coupling agent for the modification of TiO2 nanoparticles. TMPSM-modified nano-TiO2 shows excellent stability in water which makes it suitable for polymer nanocomposite processing.
- A monomer in the synthesis of reactive block copolymers via atom transfer radical polymerization. These block copolymers can be used to construct a variety of hybrid nanomaterials.
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This Item | |
|---|---|
| description 98% | description ≥97% |
| assay 98% | assay ≥97% |
| density 1.045 g/mL at 25 °C (lit.) | density 1.045 g/mL at 25 °C (lit.) |
| form liquid | form liquid |
| bp 190 °C (lit.) | bp 190 °C (lit.) |
| refractive index n20/D 1.431 (lit.) | refractive index n20/D 1.431 (lit.) |
| impurities 1% methyl alcohol from hydrolysis | impurities - |
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Storage Class
10 - Combustible liquids
WGK
WGK 1
Flash Point (°F)
197.6 °F - closed cup
Flash Point (°C)
92 °C - closed cup
PPE (personal protective equipment)
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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This product comes packaged in an amber glass bottle with a Sure/Seal crown cap.
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