593192
Cu-TMEDA catalyst
Greener Alternative
Synonym(s):
Di-μ-hydroxo-bis[(N,N,N′.N′-tetramethylethylenediamine)copper(II)] chloride
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
5 g | Check Cart for Availability | $107.00 |
About This Item
$107.00
Quality Segment
reaction suitability
core: copper, reagent type: catalyst
greener alternative product characteristics
Catalysis
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Greener Alternative Product
mp
131-132 °C (lit.)
greener alternative category
SMILES string
[H]O[Cu]Cl.[H]O[Cu]Cl.CN(C)CCN(C)C.CN(C)CCN(C)C
InChI
1S/2C6H16N2.2ClH.2Cu.2H2O/c2*1-7(2)5-6-8(3)4;;;;;;/h2*5-6H2,1-4H3;2*1H;;;2*1H2/q;;;;2*+2;;/p-4
InChI key
XSGFQMSXIWLPOB-UHFFFAOYSA-J
General description
Application
- Asymmetric conjugate addition reactions
- 1,3-dipolar cycloaddition of pyrazolidinone-based dipoles to terminal alkynes (precatalyst)
- Oxidative N-arylation of imidazoles
- Oxidative coupling copolymerization
- Tandem phosphorous-carbon bond formation-oxyfunctionalization reactions
- Benzylation and allylation of amides
1 of 1
This Item | |||
|---|---|---|---|
| description - | description - | description in anhydrous tetrahydrofuran | description ≥97% |
| reaction suitability reagent type: catalyst, core: copper | reaction suitability reagent type: catalyst, core: copper | reaction suitability core: copper, reagent type: catalyst | reaction suitability reaction type: Cross Couplings, reagent type: catalyst, reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Heck Reaction, reaction type: Negishi Coupling, reaction type: Stille Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| mp 131-132 °C (lit.) | mp >300 °C | mp - | mp 133-140 °C |
![Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I)](/deepweb/assets/sigmaaldrich/product/structures/199/763/44637b2e-b87c-42a3-abc3-3985b6cd7d5d/640/44637b2e-b87c-42a3-abc3-3985b6cd7d5d.png)
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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