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634565

Lithium perchlorate

battery grade, dry, 99.99% trace metals basis

Sustainability features

Synonym(s):

Lithium cloricum, Perchloric acid, lithium salt

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Size/SKUAvailabilityPrice
10 g

Available to ship TODAYfromMILWAUKEE

$94.30
100 g

Available to ship TODAYfromMILWAUKEE

$450.00

About This Item

Linear Formula:
LiClO4
CAS Number:
Molecular Weight:
106.39
NACRES:
NA.23
PubChem Substance ID:
EC Number:
232-237-2
MDL number:
UNSPSC Code:
12352302
Assay:
99.99% trace metals basis
Form:
powder and chunks
Solubility:
H2O: 106.4 g/L at 20 °C

$94.30


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Quality Segment

assay

99.99% trace metals basis

form

powder and chunks

reaction suitability

core: lithium, reagent type: oxidant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product, Sustainability features

mp

236 °C (lit.)

solubility

H2O: 106.4 g/L at 20 °C

application(s)

battery manufacturing
battery precursors

greener alternative category

,

SMILES string

[Li+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChI key

MHCFAGZWMAWTNR-UHFFFAOYSA-M

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.
Lithium perchlorate (LiClO4) is a neutral salt with high solubility. LiClO4 finds use as an electrolyte for lithium-sulfur batteries; it has been shown to give rise to the effective inhibition of the chemical polysulfide shuttle which subsequently boosts the columbic efficiency through the charge process.
Lithium percholate is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.

Application

LiClO4 can be used as an additive in the preparation of high-performance polyvinylidene fluoride (PVDF) fibrous membranes. It can also be doped with chitosan and starch for the fabrication of supercapacitors.
LiClO4 is used as an electrolyte salt for lithium-sulfur batteries. LiClO4 acts as a catalyst in the solvent free thiolysis of epoxides. It has been used in various organic transformations.

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62580431567936650
description

battery grade, dry, 99.99% trace metals basis

description

purum p.a., ≥98.0% (calc. based on dry substance, T), powder

description

99.99% trace metals basis

description

Technipur®, dry, 99.99% trace metals basis

form

powder and chunks

form

powder

form

granular

form

dry, powder and chunks

solubility

H2O: 106.4 g/L at 20 °C

solubility

water: soluble(lit.), alcohol: soluble(lit.)

solubility

H2O: 106.4 g/L at 20 °C

solubility

water: 106.4 g/L at 20 °C

assay

99.99% trace metals basis

assay

≥98.0% (calc. based on dry substance, T)

assay

99.99% trace metals basis

assay

99.99% trace metals basis

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

mp

236 °C (lit.)

mp

236 °C (lit.)

mp

236 °C (lit.)

mp

236 °C (lit.)

reaction suitability

core: lithium, reagent type: oxidant

reaction suitability

reagent type: oxidant

reaction suitability

reagent type: oxidant, core: lithium

reaction suitability

core: lithium


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Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3

Target Organs

Respiratory system

Storage Class

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges



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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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