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673293

Pentamethylcyclopentadienylbis(triphenylphosphine)ruthenium(II) chloride

greener alternative

Greener Alternative

solid

Synonym(s):

Cp*RuCl(PPh3)2, Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II)

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Size/SKUAvailabilityPrice
250 mg

Estimated to ship TODAYfromMILWAUKEE

$133.00
$99.75
1 g

Estimated to ship TODAYfromMILWAUKEE

$306.00

About This Item

Linear Formula:
[(C10H15)Ru(P((C6H5)3))2Cl]
CAS Number:
Molecular Weight:
796.32
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:

$99.75

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Product Name

Pentamethylcyclopentadienylbis(triphenylphosphine)ruthenium(II) chloride,

form

solid

Quality Segment

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: click chemistry

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

128 °C (D)

greener alternative category

storage temp.

2-8°C

SMILES string

Cl[Ru].C[C]1[C](C)[C](C)[C](C)[C]1C.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7

InChI

1S/2C18H15P.C10H15.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-6-7(2)9(4)10(5)8(6)3;;/h2*1-15H;1-5H3;1H;/q;;;;+1/p-1

InChI key

KLXKSZDVKAWYRT-UHFFFAOYSA-M

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is a versatile catalyst for regioselective 3+2 cycloaddition of azides and alkynes (RuAAC), producing 1,5-disubstituted triazoles. Click here for more information.

Application

Catalyst employed in the cycloaddtion of azides with acetylenes giving exclusively the 1,5-disubstitutedtriazoles in contrast to the 1,4-regiochemistry commonly observed with copper catalysis. Ruthenium catalysis also enables the use of internal acetylenes in these "click cycloaddtions".
Versatile catalyst for living radical polymerization

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This Item
667234333158701769
description

-

description

-

description

-

description

95%

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: click chemistry

reaction suitability

-

reaction suitability

core: ruthenium, reagent type: catalyst

reaction suitability

core: ruthenium, reagent type: catalyst

form

solid

form

-

form

solid

form

crystals

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

200

storage temp.

2-8°C

storage temp.

−20°C

storage temp.

-

storage temp.

2-8°C

mp

128 °C (D)

mp

143-147 °C

mp

135 °C (dec.) (lit.)

mp

>300 °C

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

sustainability

-

sustainability

-


Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable



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