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676403

(R,R)-(–)-2,3-Bis(tert-butylmethylphosphino)quinoxaline

≥95%

Synonym(s):

(R) QuinoxP®

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Size/SKUAvailabilityPrice
100 mg

Available to ship TODAY

$188.00
$196.00
500 mg

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$509.00

About This Item

Empirical Formula (Hill Notation):
C18H28N2P2
CAS Number:
Molecular Weight:
334.38
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:

$196.00

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Quality Segment

assay

≥95%

form

solid

mp

100-104 °C

functional group

phosphine

SMILES string

CP(c1nc2ccccc2nc1P(C)C(C)(C)C)C(C)(C)C

InChI

1S/C18H28N2P2/c1-17(2,3)21(7)15-16(22(8)18(4,5)6)20-14-12-10-9-11-13(14)19-15/h9-12H,1-8H3/t21-,22-/m0/s1

InChI key

DRZBLHZZDMCPGX-VXKWHMMOSA-N

General description

(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline is an air-stable C2-symmetric P-stereogenic phosphine ligand.

Application

Efficient ligand exhibiting high levels of enantiocontrol in synthetic transformations ranging from metal-catalyzed 1,4-addition of arylboronic acids to alkylative ring opening to asymmetric hydrogenation.

Features and Benefits

Advantages of the QuinoxP* Ligands:
  • It is not oxidized nor epimerized at ambient conditions in air
  • Enantioselectivities are outstanding for various reaction paradigms
  • Hydrogenations proceed under mild reaction conditions
  • Low catalyst loadings yield high TONs

Legal Information

QuinoxP is a registered trademark of Nippon Chemical Industry Co., Ltd.

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This Item
20264
description

≥95%

description

puriss., ≥99.0% (sum of enantiomers, HPLC)

assay

≥95%

assay

≥99.0% (sum of enantiomers, HPLC)

form

solid

form

solid

functional group

phosphine

functional group

-

Quality Level

100

Quality Level

100

mp

100-104 °C

mp

60-62 °C


Pictograms

Skull and crossbones

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Faceshields, Gloves



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