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76050

Palladium(II) chloride

anhydrous, 60% Pd, solid

Synonym(s):

Dichloropalladium, Palladium dichloride, Palladous chloride

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Size/SKUAvailabilityPrice
1 g

Available to ship TODAY

$188.00
5 g

Available to ship TODAY

$891.00
25 g

Available to ship TODAY

$3,600.00

About This Item

Linear Formula:
PdCl2
CAS Number:
Molecular Weight:
177.33
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
231-596-2
MDL number:

$188.00


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Product Name

Palladium(II) chloride, anhydrous, 60% Pd basis

Quality Segment

form

solid

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: inorganic catalyst

concentration

60% Pd

mp

678-680 °C (lit.)

density

4 g/mL at 25 °C (lit.)

SMILES string

Cl[Pd]Cl

InChI

1S/2ClH.Pd/h2*1H;/q;;+2/p-2

InChI key

PIBWKRNGBLPSSY-UHFFFAOYSA-L

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.
Palladium(II) chloride can be used to catalyze:
  • Cross-coupling reactions between terminal alkynes and aryl iodides or bromides under modified Sonogashira-Cassar-Heck conditions.
  • Carbonylation of organic tellurides with carbon monoxide to form corresponding methyl carboxylates.
  • Isomerization of allylic ester in acetic acid.
  • Carbonylation of amines to form isocyanates.

Other Notes

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This Item
14814323373520659
description

anhydrous, 60% Pd basis

description

anhydrous, 59-60% palladium (Pd) basis

description

99.995%

description

≥99.9%

reaction suitability

reagent type: catalyst, core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Stille Coupling, reaction type: Negishi Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling

reaction suitability

reaction type: Hiyama Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, core: palladium, reaction type: Stille Coupling, reaction type: Negishi Coupling, reagent type: catalyst, reaction type: Sonogashira Coupling, reaction type: Heck Reaction, reaction type: Suzuki-Miyaura Coupling

reaction suitability

reaction type: Hiyama Coupling, reaction type: Stille Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Suzuki-Miyaura Coupling, core: palladium, reagent type: catalyst, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling

reaction suitability

reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Heck Reaction, reagent type: catalyst
core: palladium, reaction type: Stille Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling

form

solid

form

powder

form

powder

form

-

mp

678-680 °C (lit.)

mp

678-680 °C (lit.)

mp

678-680 °C (lit.)

mp

678-680 °C (lit.)

density

4 g/mL at 25 °C (lit.)

density

4 g/mL at 25 °C (lit.)

density

4 g/mL at 25 °C (lit.)

density

4 g/mL at 25 °C (lit.)

concentration

60% Pd

concentration

59-60% Pd

concentration

-

concentration

-

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

100


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Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Storage Class

13 - Non Combustible Solids



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