Skip to Content
MilliporeSigma

Skip To

128465

Glyoxal solution

40 wt. % in H₂O, solution

Synonym(s):

Ethanedial, Oxalaldehyde

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View
Size/SKUAvailabilityPrice
5 g
Check Cart for Availability
$60.30
100 g
Check Cart for Availability
$73.50
1 kg
Check Cart for Availability
$87.10
3 kg
Check Cart for Availability
$189.00
22 kg
Check Cart for Availability
$1,020.00
50 kg
Usually ships in 5 business days. (Orders outside of US, please allow an additional 1-2 weeks for delivery)
$1,720.00

About This Item

Linear Formula:
OHCCHO
CAS Number:
Molecular Weight:
58.04
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352114
MDL number:
Beilstein/REAXYS Number:
1732463
Form:
liquid

$60.30


Check Cart for Availability

​
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist


Product Name

Glyoxal solution, 40 wt. % in H2O

vapor density

>1 (vs air)

Quality Segment

vapor pressure

18 mmHg ( 20 °C)

form

liquid

autoignition temp.

545 °F

concentration

40 wt. % in H2O

refractive index

n20/D 1.4087

solubility

water: soluble(lit.)

density

1.265 g/mL at 25 °C

functional group

aldehyde

SMILES string

[H]C(=O)C([H])=O

InChI

1S/C2H2O2/c3-1-2-4/h1-2H

InChI key

LEQAOMBKQFMDFZ-UHFFFAOYSA-N

General description

The product is 40wt.% solution of glyoxal in water. Glyoxal is a linear aliphatic dialdehyde containing two aldehyde groups. It participates in the synthesis of glyoxylic acid. It is highly reactive in nature. It can be prepared by oxidizing ethanol or acetaldehyde with nitric acid. It is widely employed in textile and paper industry.

Application

Glyoxal solution has been used as a crosslinking agent during the synthesis of DNA-containing nanoparticles in a study. It has been used as derivatizing reagent, in the precolumn fluorescence derivatization of N-terminal tryptophan containing peptides which can be separated via high performance liquid chromatography. It may also be used in the synthesis of glyoxal bis(4-phenyl-3-thiosemicarbazones)solution, which can be used in the spectrophotometric determination of palladium in catalysts.

Other Notes

This form of glyoxal is composed of 3 moles of glyoxal and 2 moles of water in a relatively stable configuration.

Disclaimer

May precipitate on storage; redissolve at 50-60 °C.

Compare Similar Items

View Full Comparison

Show Differences

1 of 1

This Item
50649157953230111
description

40 wt. % in H2O

description

BioReagent, ~40% in H2O (~8.8 M), Molecular Biology

description

technical grade

description

2.0 M in THF

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

200

solubility

water: soluble(lit.)

solubility

-

solubility

water: soluble(lit.)

solubility

-

refractive index

n20/D 1.4087

refractive index

n20/D 1.409

refractive index

-

refractive index

-

form

liquid

form

liquid

form

powder

form

-

density

1.265 g/mL at 25 °C

density

-

density

-

density

0.975 g/mL at 25 °C

concentration

40 wt. % in H2O

concentration

~40% in H2O (~8.8 M)

concentration

-

concentration

2.0 M in THF


Still not finding the right product?

Explore all of our products under Glyoxal solution


target_organs

Respiratory system

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Storage Class

10 - Combustible liquids

pictograms

Health hazardExclamation mark

signalword

Warning



Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library



Questions

1–7 of 7 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What are the storage conditions of the 100G package size supplied in a single 125 mL bottle?

    1 answer
    1. This product may be stored at room temperature. Note that any precipitates that may appear upon long term storage may be dissolved by warming the material to 50-60 °C.

      Helpful?

  4. Would the Glyoxal in this solution be stable if added to an Ethanol water mixture (50-75%) and stored for a prolonged period of time?

    1 answer
    1. Stability/shelf life information for Product 128465 dissolved in ethanol is unavailable.

      Helpful?

  5. Hello, for the Glyoxal solution 40% (128465) it is described "This form of glyoxal is composed of 3 moles of glyoxal and 2 moles of water..." What does it mean? If glyoxal solution is 40% the molar ratio glyoxal:water should be 1:5. Best regards Maja

    1 answer
    1. Product 128465 concentration is ~40% wt % in H2O which is 40 g of solid divided by 100 g of water and ~8.8 M (Moles/L). Please be mindful that the moles represent a different unit of measurement than weight percent and molarity and their ratios will vary as moles do not represent the concentration of the solution. A mole is defined as the amount of a substance that contains exactly 6.0221023 elementary entities of the given substance. 2 moles of water molecules are needed to stabilize 3 moles of glyoxal molecules as pure glyoxal is not commonly encountered since solid glyoxal around room temperature is a yellow liquid that gives off a green vapor. Commercially, it is usually handled as a 40% aqueous solution (density near 1.24 g/mL).

      Helpful?

  6. Hello, Is there a straightforward way to get this solution of glyoxal into the gas phase so that it can be introduced into an atmospheric simulation chamber for the purpose of testing developmental gas sensing systems? Kind regards, Eibhlín

    1 answer
    1. Information regarding the vapor pressure of the glyoxal cannot be provided. The conditions required for volatilization are unknown. It may be possible to begin by making an aerosol, using a bottle-type sprayer, see Product Z126306-1SET for example:
      https://www.sigmaaldrich.com/product/aldrich/z126306

      To further discuss, we kindly ask you to navigate to the link https://www.sigmaaldrich.com/techservice and click on "Product Technical Inquires" under the Products Section with all the required information so that a member of our Technical Service team can reach out to you to assist further. Thank you.

      Helpful?

  7. Hi! We want to buy 100g, but we were wondering if all the volume comes togheter in a big vial, or is it individual vials? thanks!

    1 answer
    1. The 100G package size is supplied in a single 125 mL bottle.

      Helpful?

Reviews

No rating value

Active Filters