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14023

Titanium(IV) oxysulfate

≥29% (Ti (as TiO2)), solid, technical

Synonym(s):

Titanyl sulfate

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100 g

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$63.60
1 kg

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$279.00
6 x 1 kg
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$1,580.00
50 kg
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$9,060.00

About This Item

Linear Formula:
TiOSO4 · aq
CAS Number:
Molecular Weight:
159.93 (anhydrous basis)
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:

$63.60


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Product Name

Titanium(IV) oxysulfate, ≥29% Ti (as TiO2) basis, technical

Quality Segment

grade

technical

form

solid

reaction suitability

core: titanium, reagent type: catalyst

concentration

≥29% (Ti (as TiO2))

impurities

sulfonic acid, ≤17% free acid (as H2SO4)

anion traces

chloride (Cl-): ≤500 mg/kg

cation traces

Fe: ≤500 mg/kg

SMILES string

O.O=[Ti++].[O-]S([O-])(=O)=O

InChI

1S/H2O4S.H2O.O.Ti/c1-5(2,3)4;;;/h(H2,1,2,3,4);1H2;;/q;;;+2/p-2

InChI key

SWNAGNPMPHSIJF-UHFFFAOYSA-L

Application

Titanium(IV) oxysulfate has been used as a precursor to synthesize a wide range of titanium dioxide (TiO2) photocatalysts.
It can also be used in the synthesis of freeze dried titania foams, and WO3-loaded TiO2 photocatalyst applicable for the oxidation of trans-ferulic acid to vanillin.

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This Item
33398089532769371
description

≥29% Ti (as TiO2) basis, technical

description

synthesis grade

description

27-31% H2SO4 basis, for the detection of H2O2 and ether peroxides

description

pellets, diam. × thickness 12.5 mm × 5.5 mm

reaction suitability

reagent type: catalyst, core: titanium

reaction suitability

core: titanium, reagent type: catalyst

reaction suitability

reagent type: catalyst
core: titanium

reaction suitability

core: titanium

form

solid

form

powder

form

liquid

form

pellets

Quality Level

200

Quality Level

100

Quality Level

-

Quality Level

100

cation traces

Fe: ≤500 mg/kg

cation traces

-

cation traces

-

cation traces

Pb: ≤0.1%, V: ≤0.005%, Cd: ≤0.01%, Cu: ≤0.001%, Hg: ≤0.1%, Co: ≤0.001%, Cr: ≤0.002%, Fe: ≤0.01%

impurities

≤17% free acid (as H2SO4), sulfonic acid

impurities

-

impurities

-

impurities

≤0.1% PBB (polybrominated biphenyls), ≤0.1% PBDE (polybrominated diphenyl ethers)

concentration

≥29% (Ti (as TiO2))

concentration

-

concentration

-

concentration

-


Pictograms

Corrosion

Signal Word

Danger

Hazard Codes

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Storage Class

8B - Non-combustible corrosive hazardous materials

WGK

WGK 2

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable



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Questions

1–3 of 3 Questions  
  1. Hello, what is the purity of this product. It says >= 29% Ti (as TiO2). The mass% of pure anhydrous TiOSO4 is 29.93%, and monohydrate is 26.90%. The specifications say there is < 17% free H2SO4. Is this accounted for in the reported purity?

    1 answer
    1. Yes, the mass percent of Titanium dioxide (TiO2) and Sulfuric acid (H2SO4) are accounted for and reported in the lot-specific Certificate of Analysis. A review of recent lots indicates an average TiO2 range of 32 – 34% and a H2SO4 range of 12 – 14%. This product is not tested for water content. Please see the link below to review a sample or lot-specific Certificate:
      https://www.sigmaaldrich.com/product/sial/14023#product-documentation

      Helpful?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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