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20370

tert-Butyl nitrite

technical, ≥90% (GC)

Synonym(s):

1,1-Dimethylethyl nitrite

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Size/SKUAvailabilityPrice
100 mL

Available to ship TODAYfromMILWAUKEE

$103.00
500 mL

Available to ship TODAYfromMILWAUKEE

$355.00

About This Item

Linear Formula:
(CH3)3CONO
CAS Number:
Molecular Weight:
103.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-757-0
Beilstein/REAXYS Number:
1209339
MDL number:
Assay:
≥90% (GC)
Form:
liquid

$103.00


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grade

technical

Quality Segment

assay

≥90% (GC)

form

liquid

impurities

≤8% tert-butyl alcohol

refractive index

n20/D 1.368

bp

61-63 °C (lit.)

solubility

alcohol: very soluble, chloroform: very soluble, diethyl ether: very soluble, glycerol: insoluble, water: slightly soluble

density

0.864 g/mL at 20 °C, 0.867 g/mL at 25 °C (lit.)

functional group

O-nitroso, nitroso

storage temp.

2-8°C

SMILES string

CC(C)(C)ON=O

InChI

1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3

InChI key

IOGXOCVLYRDXLW-UHFFFAOYSA-N

General description

tert-Butyl nitrite is an organic building block widely used in various organic transformations such as oxidation, diazotization, nitrosation, nitration, oximation, N-synthon, and miscellaneous reactions.

Application

tert-Butyl nitrite can be used as a reactant to synthesize aryl diazonium salts via diazotation.

Other Notes

Reagent for nitrosations, kinetics; Clean source of Me3C radicals by near-UV photolysis

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description

technical, ≥90% (GC)

description

90%

description

≥97.0% (HPLC)

description

5.0-6.0 M in decane

assay

≥90% (GC)

assay

90%

assay

≥97.0% (HPLC)

assay

-

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

solubility

alcohol: very soluble, glycerol: insoluble, chloroform: very soluble, water: slightly soluble, diethyl ether: very soluble

solubility

chloroform: very soluble(lit.), glycerol: insoluble (practically)(lit.), diethyl ether: very soluble(lit.), water: slightly soluble(lit.), alcohol: very soluble(lit.), carbon disulfide: very soluble(lit.)

solubility

methanol: soluble 1 g/10 mL, clear, colorless to slightly yellow

solubility

-

refractive index

n20/D 1.368

refractive index

n20/D 1.368 (lit.)

refractive index

-

refractive index

n20/D 1.402

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

storage temp.

2-8°C

bp

61-63 °C (lit.)

bp

61-63 °C (lit.)

bp

285 °C (lit.)

bp

-


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pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

14.0 °F - closed cup

flash_point_c

-10 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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