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Merck

254169

Cloruro d′oro(III)

99.995% trace metals basis

Sinonimo/i:

Acido cloroaurico, Acido tetracloroaurico(III), Cloruro aurico, Tetracloroaurato(III) di idrogeno

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500 MG

224,00 €

5 G

779,00 €

224,00 €


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Informazioni su questo articolo

Formula condensata:
HAuCl4 · aq
Numero CAS:
Peso molecolare:
339.79 (anhydrous basis)
Numero CE:
Numero MDL:
Codice UNSPSC:
12352302
ID PubChem:
NACRES:
NA.23

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Saggio

99.995% trace metals basis

Stato

crystals and lumps

Composizione

Degree of hydration, ~3

Impiego in reazioni chimiche

core: gold
reagent type: catalyst

tecniche

ELISA: suitable

Impurezze

≤55.0 ppm Trace Metal Analysis

Densità

3.9 g/mL at 25 °C

Stringa SMILE

O.Cl.Cl[Au](Cl)Cl

InChI

1S/Au.4ClH.H2O/h;4*1H;1H2/q+3;;;;;/p-3
OVJUDSKPNIBLOO-UHFFFAOYSA-K

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Questo articolo
5079050780520918
form

crystals and lumps

form

powder or crystals

form

powder

form

crystals and lumps

assay

99.995% trace metals basis

assay

-

assay

-

assay

≥99.9% trace metals basis

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

200

impurities

≤55.0 ppm Trace Metal Analysis

impurities

-

impurities

-

impurities

≤1000.0 ppm Trace Metal Analysis

density

3.9 g/mL at 25 °C

density

3.9 g/mL at 25 °C

density

3.9 g/mL at 25 °C

density

-

composition

Degree of hydration, ~3

composition

-

composition

-

composition

Au, 48.5-50.25%

Descrizione generale

Il cloruro di oro(III) idrato (HAuCl4) può essere usato come precursore nella sintesi dinanoparticelle di oro o come drogante di tipo p per la maggior parte delle molecole organiche coniugate. Ildrogaggio determina l′espansione del lattice cristallino e incrementa la conduttivitàper formazione di un gran numero di portatoridi carica.

Applicazioni

Il cloruro di oro(III) idrato può essere utilizzato per preparare un fotocatalizzatore a base di Au, TiO2 supportato, mediante deposizione-precipitazione con urea. Questi catalizzatori sono in grado di produrre, via reazione di “water splitting”, maggiori quantità di idrogeno a velocità di produzione più elevate

Utilizzando HAuCl4 come drogante è possibile preparare film in politiofene coniugato mediante il metodo del drogaggio in soluzione. Questi polimeri ad alta conducibilità possono essere utilizzati nel campo del sensing di vapori e dell′elettronica organica.

Per preparare nanoparticelle di oro, HAuCl4 può essere ridotto utilizzando riducenti diversi, come NaBH4, glucosio o il dendrimero poli(propilene immina)

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT RE 2 Oral

Organi bersaglio

Kidney

Codice della classe di stoccaggio

8A - Combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Domande

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Utile?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. What is the actual molecular weight of this product? 339.79 as it says in the data sheet or is there an additional weight due to the xH2O?

    1 risposta
    1. 254169 is Gold(III) chloride hydrate. The number of hydrate water is not determined as per its COA: https://www.sigmaaldrich.com/certificates/sapfs/PROD/sap/certificate_pdfs/COFA/Q14/254169-BULKMKCV5951.pdf, so the actual molecular weight is not available. 339.79 is the molecular weight of 254169 on the anhydrous basis. There will be additional weight due to the xH2O.

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  4. What is the reported purity of Product 254169, Gold (III) chloride hydrate based on, chemical or metal purity?

    1 risposta
    1. The purity (99.999%) is not the chemical purity, but rather the purity based on trace metal content.  In the case of 99.999% a maximum of 20ppm total metallic impurities would be allowed.

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  5. What is n Product 254169, Gold (III) chloride hydrate soluble in?

    1 risposta
    1. This product is soluble in water, ethanol, and ether.  Unfortunately we do not have any recorded concentrations.

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  6. How can I determine the number of hydrates present in Product 254169, Gold (III) chloride hydrate?

    1 risposta
    1. To determine the number of hydrates, you can use the following formula:   % of the metal = [(MW of metal) (# of metal atoms)] / [(MW of anhydrous product) + (x * 18g/mol)]Solving for x: x = [[(MW of metal)(#metal atoms)] - [(%of metal in product)(MW of anhydrous product)]] / [(% of metal in product) (18 g/mol)]

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  7. What is the melting point of n Product 254169, Gold (III) chloride hydrate?

    1 risposta
    1. We have never determined the melting point, however we do have a note indicating that this compound will decompose when melted.  Also the 13th Edition of the chemicals encyclopedia published by the Royal Society of Chemistry states that this compound will decompose on strong heating to form chlorine gas, hydrochloric acid gas, and metallic gold.

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  8. What is the Department of Transportation shipping information for this product?

    1 risposta
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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