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Merck

440167

(3-Glycidyloxypropyl)trimethoxysilane

≥98%

Sinonimo/i:

GLYMO

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Informazioni su questo articolo

Formula empirica (notazione di Hill):
C9H20O5Si
Numero CAS:
2530-83-8
Peso molecolare:
236.34
Beilstein:
4308125
Numero CE:
219-784-2
Numero MDL:
MFCD00005144
Codice UNSPSC:
12352103
ID PubChem:
24867573
NACRES:
NA.23

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Livello qualitativo

200

Saggio

≥98%

Stato

liquid

Indice di rifrazione

n20/D 1.429 (lit.)

P. ebollizione

120 °C/2 mmHg (lit.)

Densità

1.07 g/mL at 25 °C (lit.)

Stringa SMILE

CO[Si](CCCOCC1CO1)(OC)OC

InChI

1S/C9H20O5Si/c1-10-15(11-2,12-3)6-4-5-13-7-9-8-14-9/h9H,4-8H2,1-3H3
BPSIOYPQMFLKFR-UHFFFAOYSA-N

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Questo articolo
50059175617440183
(3-Glycidyloxypropyl)trimethoxysilane ≥98%

Sigma-Aldrich

440167

(3-Glycidyloxypropyl)trimethoxysilane

(3-Glycidyloxypropyl)triethoxysilane ≥97.0% (GC)

Sigma-Aldrich

50059

(3-Glycidyloxypropyl)triethoxysilane

(3-Mercaptopropyl)trimethoxysilane 95%

Sigma-Aldrich

175617

(3-Mercaptopropyl)trimethoxysilane

(3-Chloropropyl)trimethoxysilane ≥97%

Sigma-Aldrich

440183

(3-Chloropropyl)trimethoxysilane

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

refractive index

n20/D 1.429 (lit.)

refractive index

n20/D 1.427

refractive index

n20/D 1.444 (lit.)

refractive index

n20/D 1.419 (lit.)

density

1.07 g/mL at 25 °C (lit.)

density

1.004 g/mL at 20 °C (lit.)

density

1.057 g/mL at 25 °C (lit.)

density

1.09 g/mL at 25 °C (lit.)

bp

120 °C/2 mmHg (lit.)

bp

-

bp

213-215 °C (lit.)

bp

195 °C/750 mmHg (lit.)

assay

≥98%

assay

≥97.0% (GC)

assay

95%

assay

≥97%

form

liquid

form

-

form

liquid

form

liquid

Descrizione generale

(3-Glycidyloxypropyl)trimethoxysilane (GPTMS) is a bifunctional organosilane with three methoxy groups on one side and an epoxy ring on the other. The methoxy groups bind well with glass substrates creating a 3D matrix. The epoxy group is reactive with amides, alcohols, thiols and acids. GPTMS is highly reactive in water and can be used as a linking agent between the surface of the silica and the polymeric matrix.[1][2][3]

Applicazioni

GPTMS is widely used as a silica precursor. GPTMS alone with tetraethylortosilicate (TEOS) can be blended with chitosan for use as a filler for polymeric scaffold for bone tissue engineering.[4] It can also be coated on the surface of aluminium alloy to protect from corrosion.[5] GPTMS can used to functionalize (wrap) multi-walled carbon nanotubes (MWCNTs) which can be used as s a reinforcement in epoxy matrix nanocomposites.[2]
Pre-treatment of carbon steel with 3-(Glycidoxypropyl)trimethoxysilane enhances the dry and wet adhesion while reducing the cathotic disbondment rate of an epoxy coating[6]

Pittogrammi

Corrosion
GHS05

Avvertenze

Danger

Indicazioni di pericolo

H318,H412

Classi di pericolo

Aquatic Chronic 3 - Eye Dam. 1

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

235.4 °F - closed cup

Punto d’infiammabilità (°C)

113 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Certificati d'analisi (COA)

Lot/Batch Number
SDBB1794
SDBB1793
SDBB0475
STBL0642
STBL2731

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Functionalization of carbon nanotubes with (3-glycidyloxypropyl)-trimethoxysilane: Effect of wrapping on epoxy matrix nanocomposites.
Hoepfner, et al.
Journal of Applied Polymer Science, 133(47), 814-820 (2016)
Jadra Mosa et al.
Membranes, 9(9) (2019-08-30)
Organic/inorganic hybrid membranes that are based on GTT (GPTMS-TMES-TPTE) system while using 3-Glycidoxypropyl-trimethoxysilane (GPTMS), Trimethyletoxisilane (TMES), and Trimethylolpropane triglycidyl ether (TPTE) as precursors have been obtained while using a combination of organic polymerization and sol-gel synthesis to be used as
Ahmed A Nada et al.
International journal of biological macromolecules, 133, 538-544 (2019-04-22)
Homogenous allocation of inorganic particles in a polymeric matrix is a challenge. In this work, we discuss electrospinning of chitosan /gelatin using CS-Si (chitosan silicone hybrids) as well as the formation of homogeneously distributed Zn elements inside chitosan nanofiber through
Ngoc-Hanh Cao-Luu et al.
Journal of colloid and interface science, 536, 536-547 (2018-11-06)
How to encapsulate poly(N-isopropylacrylamide) (PNIPAM) mesoglobule cores by silica shells greatly affects the resultant nanoparticle structures. Incorporation of acrylamide (AM) unit into PNIPAM in combination with 3-glycidyloxypropyltrimethoxysilane (GLYMO, as a coupling agent) effectively induces nucleation and growth of silica on
An assessment of the corrosion protection of AA2024-T3 treated with vinyltrimethoxysilane/(3-glycidyloxypropyl) trimethoxysilane.
Dalmoro V et al.
Corrosion Science, 92(19), 200-208 (2015)
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Articoli

Synthesis of Melting Gels Using Mono-Substituted and Di-Substituted Alkoxysiloxanes

Hybrid organic-inorganic sol-gel materials containing silica were first called “ORMOSILs” in 1984.

Domande

1–9 di 9 domande  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Utile?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. I would like to know the solvent for GPTMS. What solvents does GPTMS dispersed in?

    1 risposta

    1. This product is supplied as a neat or pure liquid with a density of 1.07 g/mL. The minimum purity is 98%. This compound is soluble in water, alcohols, acetone, and most aliphatic esters at normal application levels of 45%.

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  4. I connected  GPTMS synthetically to my lipid(APTES), now my lipid cannot be dissolved in chloroform, ethanol and methanol solutions, which was previously dissolved, what solvent should I use?

    1 risposta

    1. The solubility of the GPTMS/APTES sample has not been tested, however decreasing the concentration in chloroform may be useful. Other solvents such as oils (see C8267) or a strong base, such as sodium hydroxide, may also be an option. See the link below to a publication that may be of interest:
      https://pubs.acs.org/doi/10.1021/acssuschemeng.9b06741

      If you have any further issues, please contact https://www.sigmaaldrich.com/techservice, click on "Product Technical Inquiries" under the Products Section, and provide the required information so that a member of the Technical Service team can reach out to assist further. Thank you.

      Utile?

  5. What is the viscosity of Product 440167 (3-Glycidyloxypropyl)trimethoxysilane GLYMO?

    1 risposta

    1. This material is a low viscosity liquid with an average value of about 3 centistokes. Please note that this value is not part of our specifications.

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  6. What can Product 440167, 3-Glycidyloxypropyl)trimethoxysilane GLYMO, be used for?

    1 risposta

    1. According to Dow Corning®, 3-GLYCIDOXYPROPYLTRIMETHOXYSILANE can be used as a coupling agent for many thermoset resins with glass or  mineral fillers. Specifically, it has been used as a reinforcement treatment on glass fiber to improve physical properties (especially wet strength) or as  an adhesion promoter to improve the bonding of a polymer coating or adhesive to glass, metals or other polymeric surfaces.

      Utile?

  7. What is the Department of Transportation shipping information for this product?

    1 risposta

    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  8. Is Product 440167 (3-Glycidyloxypropyl)trimethoxysilane GLYMO, equivalent to Dow's Z-6040?

    1 risposta

    1. Yes. This listing is manufactured by Dow Corning Corporation and distributed by Sigma-Aldrich.

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  9. Where can I find more detailed information about how to use Product 440167. 3-Glycidyloxypropyl)trimethoxysilane, GLYMO, in adhesion/reinforcement applications?

    1 risposta

    1. Dow Corning® has published a technical bulletin on this product, which is available by calling Technical Service at 800-231-8327.

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