PTB7

Name: PTB7
Brand: ALDRICH

average M_w 80,000-200,000, PDI ≤3.0

Sinonimo/i:

Poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl})

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Informazioni su questo articolo

Formula empirica (notazione di Hill):

(C₄₁H₅₃FO₄S₄)_n

Numero CAS:

1266549-31-8

NACRES:

NA.23

UNSPSC Code:

12352103

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Nome del prodotto

PTB7, average M_w 80,000-200,000, PDI ≤3.0

description

Band gap: 1.84 eV

form

solid

mol wt

average M_w 80,000-200,000

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

solubility

chlorobenzene: soluble
chloroform: soluble
dichlorobenzene: soluble

λ_max

680 nm (thin film)

orbital energy

HOMO -5.15 eV
LUMO -3.31 eV

M_w/M_n

2.4 +/- 0.6

PDI

≤3.0

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Questo articolo	754005	901099	753963
Sigma-Aldrich 772410 PTB7	Sigma-Aldrich 754005 PCPDTBT	Sigma-Aldrich 901099 PBDB-T	Sigma-Aldrich 753963 PBTTT-C12
form solid	form solid	form powder	form powder
description Band gap: 1.84 eV	description Band gap: 1.75 eV	description Band gap: 1.8 eV, Limited solubility in CHCl₃	description -
mol wt average M_w 80,000-200,000	mol wt average M_w 7,000-20,000	mol wt M_w >50,000 by GPC (GPC standard: PS)	mol wt M_w 20,000-80,000
greener alternative product characteristics Design for Energy Efficiency Learn more about the Principles of Green Chemistry.	greener alternative product characteristics -	greener alternative product characteristics Design for Energy Efficiency Learn more about the Principles of Green Chemistry.	greener alternative product characteristics Design for Energy Efficiency Learn more about the Principles of Green Chemistry.
sustainability Greener Alternative Product	sustainability -	sustainability Greener Alternative Product	sustainability Greener Alternative Product
solubility chlorobenzene: soluble	solubility -	solubility chlorobenzene: soluble, dichlorobenzene: soluble	solubility -

Application

High-Efficiency Organic Solar Cells (OPVs)
OPV Device Structure: ITO/PEDOT:PSS/PTB7 :PC71BM/Ca/Al

JSC = 14.9 mA/cm2
VOC = 0.75 V
FF = 0.69
PCE = 7.4%

It is majorly used as an active layer that enhances the overall performance by increasing the light absorption and improving the electron mobility of polymeric solar cells (PSCs).[1][2][3][4]

General description

PTB7 is a semiconducting polymer used in organic photovoltaics with an energy efficiency of 9.15%. It can act as an electron donor with narrow optical band gaps and excellent π-π conjugation while forming a nanocomposite with fullerenes.[5][6]

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". Hole transport organic materials allow perfect energy level alignment with the absorber layer and therefore efficient charge collection, are prone to degradation in ambient conditions.Click here for more information.

Classe di stoccaggio

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.

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Effects of additives on the morphology of solution phase aggregates formed by active layer components of high-efficiency organic solar cells.

Sylvia J Lou et al.

Journal of the American Chemical Society, 133(51), 20661-20663 (2011-12-01)

Processing additives are used in organic photovoltaic systems to optimize the active layer film morphology. However, the actual mechanism is not well understood. Using X-ray scattering techniques, we analyze the effects of an additive diiodooctane (DIO) on the aggregation of

For the bright future-bulk heterojunction polymer solar cells with power conversion efficiency of 7.4%.

Yongye Liang et al.

Advanced materials (Deerfield Beach, Fla.), 22(20), E135-E138 (2010-07-20)

Absolute measurement of domain composition and nanoscale size distribution explains performance in PTB7: PC71BM solar cells

Collins BA, et al.

Advanced Energy Materials, 3(1), 65-74 (2013)

Effect of Active Layer Thickness on the Performance of Polymer Solar Cells Based on a Highly Efficient Donor Material of PTB7-Th

Zang Y, et al.

The Journal of Physical Chemistry C, 122(29), 16532-16539 (2018)

Highly efficient tandem polymer photovoltaic cells

Sista S, et al.

Advanced Materials, 22(3), 380-383 (2010)

Visualizza tutti i documenti correlati

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High-Performance Semiconductor Polymers Based on Diketopyrrolopyrrole and Thienothiophene

The development of high-performance conjugated organic molecules and polymers has received widespread attention in industrial and academic research.

Progress for High Performance Tandem Organic Solar Cells

Professor Chen (Nankai University, China) and his team explain the strategies behind their recent record-breaking organic solar cells, reaching a power conversion efficiency of 17.3%.

Inverted Organic Photovoltaic Devices Using Zinc Oxide Nanocomposites as Electron Transporting Layer Materials

Organic photovoltaics (OPVs) represent a low-cost, lightweight, and scalable alternative to conventional solar cells. While significant progress has been made in the development of conventional bulk heterojunction cells, new approaches are required to achieve the performance and stability necessary to enable commercially successful OPVs.

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PTB7

average Mw 80,000-200,000, PDI ≤3.0