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Merck

A32608

Allyl glycidyl ether

≥99%

Sinonimo/i:

1-Allyloxy-2,3-epoxypropane, Allyl 2,3-epoxypropyl ether

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100 ML

23,80 €

500 ML

54,65 €

23,80 €

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Informazioni su questo articolo

Formula empirica (notazione di Hill):
C6H10O2
Numero CAS:
106-92-3
Peso molecolare:
114.14
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
24890754
EC Number:
203-442-4
Beilstein/REAXYS Number:
105871
MDL number:
MFCD00005143

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Nome del prodotto

Allyl glycidyl ether, ≥99%

InChI key

LSWYGACWGAICNM-UHFFFAOYSA-N

InChI

1S/C6H10O2/c1-2-3-7-4-6-5-8-6/h2,6H,1,3-5H2

SMILES string

C=CCOCC1OC1

vapor density

3.9 (vs air)

vapor pressure

4.7 mmHg ( 25 °C)

assay

≥99%

form

liquid

refractive index

n20/D 1.433 (lit.)

bp

154 °C (lit.)

density

0.962 g/mL at 25 °C (lit.)

Quality Level

200

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Questo articolo
50062377031291463
Allyl glycidyl ether ≥99%

Sigma-Aldrich

A32608

Allyl glycidyl ether

Glycidyl propargyl ether technical, ≥90% (GC)

Sigma-Aldrich

50062

Glycidyl propargyl ether

Butyl glycidyl ether 95%

Sigma-Aldrich

377031

Butyl glycidyl ether

Glycidyl isopropyl ether 98%

Sigma-Aldrich

291463

Glycidyl isopropyl ether

assay

≥99%

assay

≥90% (GC)

assay

95%

assay

98%

density

0.962 g/mL at 25 °C (lit.)

density

1.040 g/mL at 20 °C (lit.)

density

0.91 g/mL at 25 °C (lit.)

density

0.924 g/mL at 25 °C (lit.)

vapor density

3.9 (vs air)

vapor density

-

vapor density

-

vapor density

-

form

liquid

form

-

form

liquid

form

-

refractive index

n20/D 1.433 (lit.)

refractive index

n20/D 1.448

refractive index

n20/D 1.418 (lit.)

refractive index

n20/D 1.410 (lit.)

bp

154 °C (lit.)

bp

-

bp

164-166 °C (lit.)

bp

131-132 °C (lit.)

Application

AGE can be used as a terminal epoxy group in the development of adhesive surfaces by hydrosilylation process.[1] It can also be used in the synthesis of polymeric electrolytes for the fabrication of lithium batteries.[2]
Useful in hydrosilylation, including the H2PtCl6·xH2O (cat. no. 206083) catalyzed hydrosilylation of siloxanes to epoxysiloxanes.[3]

General description

Allyl glycidyl ether (AGE) is a monomer that acts as a building block in the polymerization of poly(allyl glycidyl ether) by anionic ring opening mechanism. It is industrially prepared by the reacting allyl alcohol and epichlorohydrin.[4][5]

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Classe di stoccaggio

3 - Flammable liquids

wgk

WGK 3

flash_point_f

134.6 °F - closed cup

flash_point_c

57 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
SDBB4830
STBL3518
STBL4399
SDBB0561
STBL4243

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Minimally adhesive polymer surfaces prepared from star oligosiloxanes and star oligofluorosiloxanes
Grunlan MA, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 44(8), 2551-2566 (2006)
Challa Lahari et al.
Langmuir : the ACS journal of surfaces and colloids, 26(2), 1096-1106 (2009-12-10)
Effects of changes in hydrophobicity of polymeric support on structure and activity of alpha-chymotrypsin (E.C. 3.4.21.1) have been studied with copolymers of allyl glycidyl ether (AGE) and ethylene glycol dimethacrylate (EGDM) with increasing molar ratio of EGDM to AGE (cross-link
Bhalchandra K Vaidya et al.
Bioresource technology, 99(9), 3623-3629 (2007-09-04)
Macroporous polymer particles containing surface epoxy groups were synthesized for immobilization of Candida rugosa lipase (CRL). The effect of incorporation of two different sets of monomers [allyl glycidyl ether (AGE) and glycidyl methacrylate (GMA)] and the effect of crosslinking density
Y Koyama et al.
Bioconjugate chemistry, 7(3), 298-301 (1996-05-01)
Novel poly(ethylene glycol) (PEG) derivatives having pendant amino groups were prepared by copolymerization of allyl glycidyl ether with ethylene oxide followed by chemical modification of the double bond side chains. Dropwise addition of the mixture of monomers to the anionic
A Dooms-Goossens et al.
Contact dermatitis, 33(1), 17-19 (1995-07-01)
We present a 43-year-old man who worked in the plastics industry and who suffered from an occupational dermatitis on the hands and forearms. He was found to be allergic to an epoxy silane compound that was contaminated with allyl glycidyl
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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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