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Merck

179957

Metanolo

≥99.6%, Laboratory Reagent grade

Sinonimo/i:

Alcol metilico

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1 L

30,00 €

2.5 L

58,10 €

30,00 €


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Informazioni su questo articolo

Formula condensata:
CH3OH
Numero CAS:
Peso molecolare:
32.04
NACRES:
NA.05
PubChem Substance ID:
eCl@ss:
39020101
UNSPSC Code:
12352104
EC Number:
200-659-6
MDL number:
Beilstein/REAXYS Number:
1098229
Grade:
Laboratory Reagent
Assay:
≥99.6%
Bp:
64.7 °C (lit.)
Vapor pressure:
410 mmHg ( 50 °C)
97.68 mmHg ( 20 °C)

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Nome del prodotto

Metanolo, Laboratory Reagent, ≥99.6%

InChI key

OKKJLVBELUTLKV-UHFFFAOYSA-N

InChI

1S/CH4O/c1-2/h2H,1H3

SMILES string

CO

grade

Laboratory Reagent

vapor density

1.11 (vs air)

vapor pressure

410 mmHg ( 50 °C)
97.68 mmHg ( 20 °C)

assay

≥99.6%

form

liquid

autoignition temp.

725 °F

expl. lim.

36 %

dilution

(for analytical testing)

impurities

≤0.01% alkalinity (as NH3)
≤0.03% acidity (as HCOOH)
≤0.1% water

evapn. residue

≤0.01%

refractive index

n20/D 1.329 (lit.)

bp

64.7 °C (lit.)

mp

−98 °C (lit.)

density

0.791 g/mL at 25 °C (lit.)

format

neat

storage temp.

room temp

Quality Level

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Questo articolo
17933732213-M320390
Metanolo Laboratory Reagent, ≥99.6%

Sigma-Aldrich

179957

Metanolo

Metanolo ACS reagent, ≥99.8%

Sigma-Aldrich

179337

Metanolo

Metanolo puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.8% (GC)

Sigma-Aldrich

32213-M

Metanolo

Metanolo ACS reagent, ≥99.8%

Sigma-Aldrich

320390

Metanolo

assay

≥99.6%

assay

≥99.8%

assay

≥99.8% (GC)

assay

≥99.8%

grade

Laboratory Reagent

grade

ACS reagent

grade

ACS reagent, puriss. p.a.

grade

ACS reagent

Quality Level

100

Quality Level

100, 200

Quality Level

-

Quality Level

200

form

liquid

form

liquid

form

liquid

form

liquid

refractive index

n20/D 1.329 (lit.)

refractive index

n20/D 1.329 (lit.)

refractive index

n20/D 1.329 (lit.)

refractive index

n20/D 1.329 (lit.)

impurities

≤0.01% alkalinity (as NH3), ≤0.1% water, ≤0.03% acidity (as HCOOH)

impurities

H2SO4, passes test (darkened), MnO4- reducers, passes test, ≤0.0002 meq/g Titr. base, ≤0.0003 meq/g Titr. acid, ≤0.001% acetaldehyde, ≤0.001% acetone, ≤0.001% formaldehyde, ≤0.1% water

impurities

≤0.00005% free alkali (as NH3), ≤0.0001% formaldehyde, ≤0.00025% KMnO4 red. matter (as O), ≤0.0005% non-volatile matter, ≤0.001% acetaldehyde, ≤0.001% acetone (GC), ≤0.05% water (Karl Fischer), ≤0.1% ethanol (GC)

impurities

H2SO4, passes test (darkened), MnO4- reducers, passes test, ≤0.0002 meq/g Titr. base, ≤0.0003 meq/g Titr. acid, ≤0.001% acetaldehyde, ≤0.001% acetone, ≤0.001% formaldehyde, ≤0.1% water

Application

Methanol may be used to compose the binary mixtures with acetonitrile in a study. Experimental evaluation of the values of dielectric constant and dielectric loss of these binary mixtures at microwave frequencies at 300°C has been reported.[1]

General description

Methanol is an industrially important alcohol.[1] Its thermochemical conversion to C2-C10 hydrocarbons in the presence of shape-selective zeolites has been reported.[2] Its oxidation on Ru-Pt catalyst system by ruthenium ad-atoms has been proposed.[3] It participates in the purification step during the synthesis of pyocyanin, a toxic compound found in Pseudomonas aeruginosa.[4]
Methanol is an organic solvent that can be synthesized from syngas in the presence of CuO/ZnO/Al2O3 catalysts.[5] It is an ideal candidate as a hydrogen source in fuel cell technology due to its high H/C ratio, low propensity for soot generation, relatively low reforming temperature and as it exists in liquid state at room temperature.[6][7] In a direct methanol fuel cell (DMFC), methanol undergoes oxidation with air to generate electricity. The olefins (ethylene or propylene) formed from methanol via MTO (methanol-to-olefins) process, can be an alternative to oil and gas to produce hydrocarbon fuels.[8]

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

target_organs

Eyes,Central nervous system

Classe di stoccaggio

3 - Flammable liquids

wgk

WGK 2

flash_point_f

49.5 °F - closed cup

flash_point_c

9.7 °C - closed cup


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I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.

Visita l’Archivio dei documenti

Dielectric behavior of acetonitrile+ methanol binary mixtures at microwave frequency.
Jogdand AP and Kadam PL.
IOSR Journal of Applied Physics, 2278-4861 (2014)
Standardized chemical synthesis of Pseudomonas aeruginosa pyocyanin.
Cheluvappa R.
Gastroenterologia y hepatologia, 22, 1350-1351 (2007)
Catalytic carbon dioxide hydrogenation to methanol: A review of recent studies.
Jadhav SG, et al.
Chemical Engineering Research and Design, 92(11), 2557-2567 (2014)
Beyond oil and gas: the methanol economy.
Olah GA.
Angewandte Chemie (International Edition in English), 44(18), 2636-2639 (2005)
Review of methanol reforming-Cu-based catalysts, surface reaction mechanisms, and reaction schemes.
Yong ST, et al.
International Journal of Hydrogen Energy, 38(22), 9541-9552 (2013)

Domande

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Utile?

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