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C1909

クエン酸 一水和物

ACS reagent grade, ≥99.0%, powder

別名:

2-hydroxy-1,2,3-propanetricarboxylic acid monohydrate

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容量カタログ番号在庫状況単価
25 g
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¥8,160
500 g

在庫あり出荷可能from市川市大町368

¥11,200
1 kg
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¥17,700
2.5 kg
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¥28,200
12 kg
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¥107,000

この商品について

化学式:
HOC(COOH)(CH2COOH)2 · H2O
CAS番号:
分子量:
210.14
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
201-069-1
MDL number:
Beilstein/REAXYS Number:
4018641
Assay:
≥99.0%
Form:
powder
Grade:
ACS reagent

¥8,160


カートの在庫状況を確認する

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製品名

クエン酸 一水和物, ACS reagent, ≥99.0%

grade

ACS reagent

Quality Level

assay

≥99.0%

form

powder

impurities

Substances carbonizable by hot sulfuric acid, passes test, ≤0.005% Insoluble matter

ign. residue

≤0.02%

pH

(1.8 at 50 g/l at 20 °C)

pKa 

(1) 3.13, (2) 4.76, (3) 6.4

solubility

H2O: soluble 54 % (w/w) at 10 °C (Citric acid in water), H2O: 59.2 % (w/w) at 20 °C (Citric acid in water), H2O: 84.0 % (w/w) at 100 °C (Citric acid in water)

anion traces

chloride (Cl-): ≤0.001%, oxalate (C2O42-): passes test (limit about 0.05%), phosphate (PO43-): ≤0.001%, sulfate (SO42-): ≤0.002%

cation traces

Fe: ≤3 ppm, Pb: ≤2 ppm

functional group

carboxylic acid

SMILES string

OC(CC(O)(C(O)=O)CC(O)=O)=O.O

InChI

1S/C6H8O7.H2O/c7-3(8)1-6(13,5(11)12)2-4(9)10;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);1H2

InChI key

YASYEJJMZJALEJ-UHFFFAOYSA-N

General description

クエン酸一水和物は有機酸です。クエン酸一水和物水溶液のモルエンタルピーは、ΔsolHm (298.15 K, m = 0.0203 molkg-1) = (29061±123)Jmol-1であることが報告されています。クエン酸一水和物は、クエン酸合成時にクエン酸溶液の母液から20~25°Cで結晶化することで生成できます。その結晶成長動態の研究から、サイズに応じて線形に成長することが示されています。

クエン酸一水和物は、食品や飲料製品の天然防腐剤として使用される有機弱酸です。

Application

クエン酸一水和物は、68Ga予備精製のためのアセトン法に使用するクエン酸溶液の調製および放射線標識法に使用されました。[1]
クエン酸一水和物には次の用途があります:
  • 溶融押出成形Eudragit RS PO錠からの塩酸ジルチアゼムの放出を改善する放出調節剤として。[2]
  • 生体内顕微鏡検査用の血小板の調製に使用するクエン酸バッファーを調製するため。[3]
  • 細菌酵素の電気泳動に使用するトリスクエン酸バッファーを調製するため。[4]

類似品目との比較

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当該品目
33114C7129C0706
grade

ACS reagent

grade

ACS reagent, puriss. p.a.

grade

reagent grade

grade

-

assay

≥99.0%

assay

99.5-100.5% (calc. on anhydrous substance), 99.5-102%

assay

≥98% (GC/titration)

assay

≥99.5%

Quality Level

200

Quality Level

200

Quality Level

300

Quality Level

200

form

powder

form

solid

form

powder

form

powder

solubility

H2O: soluble 54 % (w/w) at 10 °C (Citric acid in water), H2O: 84.0 % (w/w) at 100 °C (Citric acid in water), H2O: 59.2 % (w/w) at 20 °C (Citric acid in water)

solubility

-

solubility

H2O: 100 mg/mL, clear, colorless (Turbidity)

solubility

H2O: 1 M, clear, colorless

pH

(1.8 at 50 g/l at 20 °C)

pH

-

pH

-

pH

1.85 (25 °C, 50 g/L)


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pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - STOT SE 3

target_organs

Respiratory system

保管分類

11 - Combustible Solids

wgk

WGK 1

flash_point_f

345.0 °F - closed cup

flash_point_c

173.9 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves



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資料

LC-MS/MS-based determination of 19 sulfonamides, 13 quinolones, and 3 tetracycline drug residues in pork meat samples using Supel™ Swift HLB for extraction.


Eco-friendly rice husk pre-treatment for preparing biogenic silica: Gluconic acid and citric acid comparative study
Setiawan WK and Chiang KY
Chemosphere, 179, 130541-130541 (2021)
Size dependency of citric acid monohydrate growth kinetics.
Bravi M and Mazzarotta B.
Chemical Engineering Journal, 70(3), 203-207 (1998)
Michael K Schultz et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 76, 46-54 (2012-10-03)
A new NaCl based method for preparation of gallium-68 labeled radiopharmaceuticals has been adapted for use with an automated gallium-68 generator system. The method was evaluated based on 56 preparations of [(68)Ga]DOTATOC and compared to a similar acetone-based approach. Advantages



グローバルトレードアイテム番号

カタログ番号GTIN
C1909-25G04061833468869
C1909-12KG04061833468807
C1909-1KG04061835555826
C1909-2.5KG04061833468838
C1909-500G04061835555833

質問

1–3/3 質問  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 回答
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      役に立ちましたか?

  2. I need to prepare 100 ml of 1 molar citric acid solution. How do I prepare this and which product do I need to buy?

    1 回答
    1. The volume of 100 mL is equivalent to 0.1 Liters. And 1 molar (1 mole per liter) times 0.1 liters equals 0.1 moles. The molecular weight for Citric Acid Monohydrate is 210.14 grams per mole. And 0.1 moles times 210.14 grams per mole equals 21.0 grams. So to prepare the solution, dissolve 21.0 grams of citric acid monohydrate in about 75 mL of pure water, then bring the final volume to 100 mL. Citric Acid Monohydrate is very soluble in water.
      As far as which product to buy, many grades of citric acid and citric acid monohydrate are listed. Please contact your local Technical Service group and describe your intended application so that they can help you choose the appropriate grade.

      役に立ちましたか?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 回答
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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