339601
1-Bromo-4-(trifluoromethoxy)benzene
99%
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About This Item
Linear Formula:
BrC6H4OCF3
CAS Number:
Molecular Weight:
241.01
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
206-979-2
MDL number:
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Product Name
1-Bromo-4-(trifluoromethoxy)benzene, 99%
InChI key
SEAOBYFQWJFORM-UHFFFAOYSA-N
InChI
1S/C7H4BrF3O/c8-5-1-3-6(4-2-5)12-7(9,10)11/h1-4H
SMILES string
FC(F)(F)Oc1ccc(Br)cc1
assay
99%
form
liquid
refractive index
n20/D 1.461 (lit.)
bp
80 °C/50 mmHg (lit.)
density
1.622 g/mL at 25 °C (lit.)
functional group
bromo
fluoro
Quality Level
Related Categories
Application
1-Bromo-4-(trifluoromethoxy)benzene was used in the synthesis of 4-{[4-[(2-ethylhexyloxy)-6-(4-morpholinylmethyl)-4-trifluoromethyl][1,1-biphenyl]-3-yl]methyl}morpholine.[1]
General description
1-Bromo-4-(trifluoromethoxy)benzene on treatment with lithium diisopropylamide (LIDA) at -100°C gives 5-bromo-2-(trifluoromethoxy)phenyllithium and at -75°C it eliminates lithium bromide, thus generating 1,2-dehydro-4-(trifluoromethoxy)benzene.[2]
signalword
Warning
hcodes
Hazard Classifications
Skin Irrit. 2
Storage Class
10 - Combustible liquids
wgk
WGK 1
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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1, 2-Didehydro-3-and-4-(trifluoromethoxy) benzene: The ?Aryne? Route to 1-and 2-(Trifluoromethoxy) naphthalenes.
Schlosser M and Castagnetti E.
European Journal of Organic Chemistry, 2001(21), 3991-3997 (2001)
Novel poly (p-phenylenevinylene) s derivatives with CF3-phenyl substituent for light-emitting diodes.
Jin Y, et al.
Bull. Korean Chem. Soc., 26(5), 795-801 (2005)
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