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Simple iron-amine catalysts for the cross-coupling of aryl Grignards with alkyl halides bearing beta-hydrogens.

Chemical communications (Cambridge, England) (2005-08-16)
Robin B Bedford, Duncan W Bruce, Robert M Frost, Michael Hird
ABSTRACT

Mixtures of iron(III) chloride and appropriate amine ligands are active catalysts for the coupling of aryl Grignard reagents with primary and secondary alkyl halide substrates bearing beta-hydrogens, under mild and simple reaction conditions.

MATERIALS
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Brand
Product Description

Sigma-Aldrich
(Bromomethyl)cyclopropane, 97%

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