If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
189898
Methylmagnesium bromide solution
3.0 M in diethyl ether
Synonym(s):
Bromomethylmagnesium
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
50 mL | Available to ship TODAY | $61.70 |
100 mL | Available to ship TODAY | $112.00 |
4 x 25 mL | Available to ship onNovember 05, 2026fromMILWAUKEE | $123.00 |
800 mL | Available to ship TODAY | $530.00 |
4 x 100 mL | Available to ship TODAY | $580.00 |
8 L | Check Cart for Availability | $2,270.00 |
18 L | Available to ship onNovember 05, 2026fromMILWAUKEE | $3,530.00 |
About This Item
$61.70
Available to ship TODAYDetails
Quality Segment
form
liquid
reaction suitability
reaction type: Grignard Reaction
packaging
Kilo-Lab™ of , Sure/Seal™ of
concentration
3.0 M in diethyl ether
density
1.035 g/mL at 25 °C
SMILES string
C[Mg]Br
InChI
1S/CH3.BrH.Mg/h1H3;1H;/q;;+1/p-1
InChI key
AVFUHBJCUUTGCD-UHFFFAOYSA-M
General description
Application
- 3S-(Boc-amino)-2,4-dimethyl-2-pentanol and methyl tert-butyl (S)-sulfoxide.
- Methyl potassium polyimide (K-PIM-1) (MeMgBr).
- 3(4R)-{3(2R,3S)-[4′-(1′-triphenylmethyl)imidazole]-2-bromo-1-oxobutyl)-4-phenyl2-oxazolidinone
- Benzyl 2-(2-oxopropyl)piperidine-1-carboxylate
- (R*, R*) 1-[1-(1-phenylethyl)pyrrolidin-2-yl]propan-2-one)
Packaging
Legal Information
1 of 1
This Item | |||
|---|---|---|---|
| description 3.0 M in diethyl ether | description ~3.2 M in 2-methyltetrahydrofuran | description 1.0 M in dibutyl ether | description 1.4 M in THF: toluene (1:3) |
| concentration 3.0 M in diethyl ether | concentration ~3.2 M in 2-methyltetrahydrofuran | concentration 1.0 M in dibutyl ether | concentration 1.4 M in THF: toluene (1:3) |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 200 |
| form liquid | form liquid | form - | form - |
| density 1.035 g/mL at 25 °C | density 1.117 g/mL at 25 °C | density 0.856 g/mL at 25 °C | density 1.018 g/mL at 25 °C |
| packaging Sure/Seal™ of , Kilo-Lab™ of | packaging Sure/Seal™ of | packaging Sure/Seal™ of | packaging Sure/Seal™ of |
| reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction |
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Signal Word
Danger
Hazard Codes
Precautionary Statements
Target Organs
Central nervous system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
Flash Point (°F)
-40.0 °F - closed cup
Flash Point (°C)
-40 °C - closed cup
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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