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761001

Lithium nickel manganese cobalt oxide

greener alternative

powder, <0.5 μm particle size, >98%

Synonym(s):

NMC

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10 G

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$242.00

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About This Item

Linear Formula:
LiNi0.33Mn0.33Co0.33O2
CAS Number:
346417-97-8
MDL number:
MFCD00460869
UNSPSC Code:
26111700
NACRES:
NA.23

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grade

battery grade

assay

>98%

form

powder

mol wt

Mw 96.46 g/mol

composition

LiNi0.33Mn0.33Co0.33O2

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

particle size

<0.5 μm

mp

>290 °C (lit.)

density

2.11 g/cm3

application(s)

battery manufacturing

greener alternative category

, Enabling

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This Item
725110765163760994
Lithium nickel manganese cobalt oxide powder, &lt;0.5&#160;&#956;m particle size, &gt;98%

Sigma-Aldrich

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Lithium nickel manganese cobalt oxide

Lithium manganese nickel oxide spinel, powder, &lt;0.5&#160;&#956;m particle size (BET), &gt;99%

Sigma-Aldrich

725110

Lithium manganese nickel oxide

Lithium nickel manganese cobalt oxide electrode sheet, aluminum substrate, size 5&#160;in. × 10&#160;in.

Sigma-Aldrich

765163

Lithium nickel manganese cobalt oxide

Lithium nickel cobalt aluminium oxide powder, &lt;0.5&#160;&#956;m particle size, &gt;98%

Sigma-Aldrich

760994

Lithium nickel cobalt aluminium oxide

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

particle size

<0.5 μm

particle size

<0.5 μm (BET)

particle size

8-12 μm (typical)

particle size

<0.5 μm

grade

battery grade

grade

battery grade

grade

battery grade

grade

battery grade

composition

LiNi0.33Mn0.33Co0.33O2

composition

Li2Mn3NiO8

composition

loading, ≥80%

composition

LiNi0.8Co0.15Al0.05O2

form

powder

form

powder

form

-

form

powder

application(s)

battery manufacturing

application(s)

battery manufacturing

application(s)

battery manufacturing

application(s)

battery manufacturing

General description

Lithium nickel manganese cobalt oxide (NMC) is a class of electrode material that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.[1][2][3][4]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

NMC is a novel lithium insertion electrode material for advanced lithium-ion batteries. Mn doping significantly increases the thermal stability besides increasing the electrochemical charge-discharge behavior.
NMC111 (lithium nickel-manganese-cobalt oxide with a stoichiometry of 1:1:1) is a promising cathode material used in advanced lithium-ion batteries, particularly for electric vehicle applications, due to its high energy density and long cycle life. NMC111 powder has a layered crystal structure that enables efficient, reversible lithium-ion diffusion, which is essential for good electrochemical performance. Manganese doping improves the thermal stability of the material while enhancing its electrochemical charge-discharge behavior. Compared to other NMC materials, NMC111 has a higher thermal stability and is less prone to thermal runaway, making it a safer option for battery applications.

Features and Benefits

Our NMC111 has engineered improvements over other LiNMC materials including thermal stability and high conductivity:
  • More Reliable
  • Longer Cycle Life
  • Bulk and Pilot Scale Available

Legal Information

Product of Engi-Mat Co.

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pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Warning

hcodes

H317,H351

Hazard Classifications

Carc. 2 - Skin Sens. 1

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCZ3578
MKCW1642
MKCT7459
MKCS3197
MKCQ4516

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Impedance change and capacity fade of lithium nickel manganese cobalt oxide-based batteries during calendar aging
Schmitt J, et al.
Journal of Power Sources, 353, 183-194 (2017)
Belharouak, I.; et al.
Journal of Power Sources, 123, 247-247 (2003)
A bi-functional lithium difluoro (oxalato) borate additive for lithium cobalt oxide/lithium nickel manganese cobalt oxide cathodes and silicon/graphite anodes in lithium-ion batteries at elevated temperatures
Lee SJ, et al.
Electrochimica Acta, 137, 1-8 (2014)
Choi, J.; Manthiram, A.; J.
Journal of the Electrochemical Society, 152, A1714-A1714 (2005)
Electrodes with high power and high capacity for rechargeable lithium batteries
Kang K, et al.
Science, 311(5763), 977-980 (2006)
View All Related Papers

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Electrode Materials for Li-ion Batteries

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Advances in Li-Metal Fluoride Battery

Professor Qiao's review explores stable microstructures for lithium metal fluoride batteries, advancing energy storage technologies.

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Protocols

Streamlined Electrode Fabrication: A User-Friendly Guide

Guide for fabricating NMC811 cathode electrodes, detailing procedures for optimal performance in lithium-ion batteries.

Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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