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223859 Sigma-Aldrich

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide

98%

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Properties

Related Categories C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents More...
assay   98%
reaction suitability   reaction type: C-C Bond Formation
mp   193-195 °C (lit.)
storage temp.   room temp
SMILES string   [Br-].C1COC(C[P+](c2ccccc2)(c3ccccc3)c4ccccc4)O1
InChI   1S/C22H22O2P.BrH/c1-4-10-19(11-5-1)25(18-22-23-16-17-24-22,20-12-6-2-7-13-20)21-14-8-3-9-15-21;/h1-15,22H,16-18H2;1H/q+1;/p-1
InChI key   FRHRVQQUICVJDG-UHFFFAOYSA-M

Description

Application

Reactant for:
• Preparation of a ratiometric fluorescent probe for specific detection of cysteine over homocysteine and glutathione
• Microwave-assisted synthesis of KN-93 as inhibitor of calmodulin kinase II
• Preparation of fluorinated spirobenzofuran piperidines as s1 receptor ligands
• Synthesis and antitumor agents
• Regio-selective preparation of indole derivatives via rhodium-catalyzed domino hydroformylation/indolization

Packaging

5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles
Peer-Reviewed Papers
15

References

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