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714836

Iodine monochloride solution

1 M in acetic acid

Synonym(s):

Chloroiodide solution, Wijs solution

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Size/SKUAvailabilityPrice
100 mL
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$206.00

About This Item

Linear Formula:
ICl
CAS Number:
Molecular Weight:
162.36
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587194
Form:
solution

$206.00


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form

solution

Quality Segment

reaction suitability

reaction type: Halogenations

concentration

1 M in acetic acid

density

1.143 g/mL at 25 °C

SMILES string

ClI

InChI

1S/ClI/c1-2

InChI key

QZRGKCOWNLSUDK-UHFFFAOYSA-N

General description

Iodine monochloride is an inorganic reagent used in the iodination and chloroiodination of aromatic and unsaturated compounds, respectively. It is also used to cleave carbon-metal bonds.

Application

Iodine monochloride can be used:
  • As a reagent in the preparation of α-iodo β-ketosulfones from β-ketosulfones.
  • In the synthesis of 3-(4-bromo-2-methylphenyl)-4-iodosydnone, which is further used to prepare substituted pyrazoles.


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This Item
402990291048208221
description

1 M in acetic acid

description

ACS reagent, 1.10±0.1 I/Cl ratio basis

description

1.0 M in methylene chloride

description

reagent grade, ≥95%

reaction suitability

reaction type: Halogenations

reaction suitability

reaction type: Halogenations

reaction suitability

reaction type: Halogenations

reaction suitability

-

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

200

density

1.143 g/mL at 25 °C

density

3.24 g/mL at 25 °C (lit.)

density

1.42 g/mL at 25 °C

density

3.24 g/mL at 25 °C (lit.)

form

solution

form

solid or liquid

form

liquid

form

solid or liquid

concentration

1 M in acetic acid

concentration

-

concentration

1.0 M in methylene chloride, 0.95-1.10 M (by Na2S2O3, titration)

concentration

-


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Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Codes

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

105.1 °F

Flash Point (°C)

40.6 °C



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