335002
Carbonyldihydridotris(triphenylphosphine)ruthenium(II)
Sustainability features
Synonym(s):
Dihydridocarbonyltris(triphenylphosphine)ruthenium
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
1 g | Available to ship TODAYfromMILWAUKEE | $188.00 |
About This Item
Quality Segment
reaction suitability
core: ruthenium, reagent type: catalyst
reaction type: C-H Activation
sustainability
Sustainability features
mp
161-163 °C (lit.)
SMILES string
[RuH2].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI
1S/3C18H15P.CO.Ru.2H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h3*1-15H;;;;
InChI key
MLIYPCQSOXNTLJ-UHFFFAOYSA-N
General description
Application
- Catalyst for conversion of 1,4-alkynediols into pyrroles
- Catalyst for oxidation of primary alcohols to methyl esters
- Catalyst for rearrangement of oximes to amides
- Catalyst for C-C coupling via directed C-H activation
- Catalyst for enyne cyclization
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This Item | |||
|---|---|---|---|
| description - | description - | description - | description 97% |
| reaction suitability core: ruthenium, reagent type: catalyst | reaction suitability reagent type: catalyst, core: ruthenium | reaction suitability core: ruthenium, reagent type: catalyst | reaction suitability core: ruthenium, reagent type: catalyst |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| mp 161-163 °C (lit.) | mp 204-206 °C (dec.) (lit.) | mp 181-183 °C (lit.) | mp 223-244 °C |
| greener alternative product characteristics Catalysis | greener alternative product characteristics - | greener alternative product characteristics - | greener alternative product characteristics - |
| greener alternative category | greener alternative category - | greener alternative category - | greener alternative category - |
| sustainability Greener Alternative Product | sustainability - | sustainability - | sustainability - |
Signal Word
Warning
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
Storage Class
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
dust mask type N95 (US), Eyeshields, Gloves
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