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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
697230
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
powder
Sustainability features
Synonym(s):
Pd(dppf)Cl2
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
1 g | Check Cart for Availability | $133.00 |
5 g | Check Cart for Availability | $477.00 |
25 g | Please contact Customer Service for Availability | $1,490.00 |
250 g | Please contact Customer Service for Availability | $12,110.00 |
About This Item
Product Name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II),
form
powder
Quality Segment
reaction suitability
core: palladium, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Sustainability features
mp
266-283 °C (lit.)
SMILES string
[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
InChI
1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2
InChI key
JCWIWBWXCVGEAN-UHFFFAOYSA-L
General description
Application
- Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
- Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
- Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.
1 of 1
This Item | |||
|---|---|---|---|
| description - | description Umicore | description ≥97.0% (AT) | description - |
| reaction suitability reaction type: Sonogashira Coupling, reaction type: Cross Couplings, reaction type: Heck Reaction, core: palladium, reaction type: Negishi Coupling, reagent type: catalyst | reaction suitability - | reaction suitability reaction type: Cross Couplings, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Hiyama Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reagent type: ligand, reagent type: catalyst | reaction suitability core: palladium, reaction type: Suzuki-Miyaura Coupling, reaction type: Sonogashira Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst |
| form powder | form powder | form powder | form solid |
| Quality Level 200 | Quality Level 100 | Quality Level 200 | Quality Level 200 |
| mp 266-283 °C (lit.) | mp 266-283 °C (lit.) | mp - | mp - |
| greener alternative category | greener alternative category | greener alternative category - | greener alternative category |
| sustainability Greener Alternative Product | sustainability Greener Alternative Product | sustainability - | sustainability Greener Alternative Product |
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Storage Class
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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