908487
N-(tert-butyl)-N-((ethoxycarbonothioyl)thio)-2,3,4,5,6-pentafluorobenzamide
≥95%
Synonym(s):
Alexanian xanthylation reagent
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| Size/SKU | Availability | Price |
|---|---|---|
1 g | Check Cart for Availability | $196.00 |
About This Item
Empirical Formula (Hill Notation):
C14H14F5NO2S2
Molecular Weight:
387.39
NACRES:
NA.22
UNSPSC Code:
12352111
eCl@ss:
32150917
Assay:
≥95%
Form:
powder or crystals
assay
≥95%
form
powder or crystals
reaction suitability
reaction type: Halogenations
mp
46-48 °C
functional group
amine, fluoro
storage temp.
−20°C
Application
As reported by the Alexanian laboratory, this reagent is used for site-selective, intermolecular decarboxylative xanthylation leading to the rapid diversification of carboxylic acids. Once installed, the xanthate group provides direct access to diverse product analogues via several aliphatic C-H transformations, including halogenation, deuteration, vinylation, hydroxylation. Product is best stored in foil-wrapped vials in the freezer when not in use; however, it can be weighed out on the bench without risk of decomposition.
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This Item | |||
|---|---|---|---|
| description ≥95% | description - | description 97% | description 97% |
| assay ≥95% | assay - | assay 97% | assay 97% |
| reaction suitability reaction type: Halogenations | reaction suitability - | reaction suitability - | reaction suitability - |
| form powder or crystals | form solid | form - | form - |
| mp 46-48 °C | mp 40-46 °C | mp 65-69 °C (lit.) | mp - |
| storage temp. −20°C | storage temp. −20°C | storage temp. - | storage temp. - |
| functional group fluoro, amine | functional group amine, fluoro | functional group amine, carboxylic acid | functional group amine, bromo |
Storage Class
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
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