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334901

Tetramethylammonium hydroxide solution

25 wt. % in methanol, solution

Synonym(s):

N,N,N-trimethyl-methanaminium hydroxide, TMAH, TMAOH

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100 mL

Available to ship TODAYfromMILWAUKEE

$60.40
$51.34
500 mL

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$147.00
4 x 100 mL

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$234.00
$175.50

About This Item

Linear Formula:
(CH3)4N(OH)
CAS Number:
Molecular Weight:
91.15
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Beilstein/REAXYS Number:
3558708
Concentration:
25 wt. % in methanol
Form:
liquid

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Product Name

Tetramethylammonium hydroxide solution, 25 wt. % in methanol

vapor pressure

17.5 mmHg ( 20 °C)

Quality Segment

form

liquid

reaction suitability

core: ammonium, reaction type: phase-transfer

concentration

25 wt. % in methanol

impurities

≤10% water, ≤2% chloride

density

0.866 g/mL at 25 °C

functional group

amine

SMILES string

[OH-].C[N+](C)(C)C

InChI

1S/C4H12N.H2O/c1-5(2,3)4;/h1-4H3;1H2/q+1;/p-1

InChI key

WGTYBPLFGIVFAS-UHFFFAOYSA-M

General description

Tetramethylammonium hydroxide is a strong base used in the o-alkylation of phenolic and carboxylic OH groups.

Tetramethylammonium hydroxide is a quaternary ammonium salt generally used as an anisotropic etchant for silicon due to its high silicon etching rate.

Application

Tetramethylammonium hydroxide solution (25 wt.% solution in methanol) may be used in the synthesis of zirconium oxides via a modified sol-gel method with potential application as catalyst materials in CO hydrogenation.

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This Item
426318328251
description

25 wt. % in methanol

description

ACS reagent

description

10 wt. % in H2O

concentration

25 wt. % in methanol

concentration

1.0 M±0.02 M in H2O

concentration

10 wt. % in H2O

Quality Level

200

Quality Level

200

Quality Level

100

form

liquid

form

liquid

form

-

impurities

≤10% water, ≤2% chloride

impurities

-

impurities

-

density

0.866 g/mL at 25 °C

density

1.005 g/mL at 25 °C

density

1.006 g/mL at 25 °C

vapor pressure

17.5 mmHg ( 20 °C)

vapor pressure

-

vapor pressure

17.5 mmHg ( 20 °C)


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Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT RE 1 Dermal - STOT SE 1

Target Organs

Eyes,Central nervous system, Liver,thymus

Storage Class

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

80.6 °F - closed cup

Flash Point (°C)

27 °C - closed cup

PPE (personal protective equipment)

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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