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Merck

695068

Fluorwasserstoffsäure

ACS reagent, 48%

Synonym(e):

HF

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25 ML

CHF 68.20

500 ML

CHF 103.00

CHF 68.20


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Über diesen Artikel

Empirische Formel (Hill-System):
HF
CAS-Nummer:
Molekulargewicht:
20.01
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352106
EC Number:
231-634-8
MDL number:

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Produktname

Fluorwasserstoffsäure, ACS reagent, 48%

InChI key

KRHYYFGTRYWZRS-UHFFFAOYSA-N

InChI

1S/FH/h1H

SMILES string

[H+].[F-]

grade

ACS reagent

vapor density

1.27 (vs air)

vapor pressure

25 mmHg ( 20 °C)

assay

48%

form

liquid

Quality Level

impurities

≤0.5 ppm As (Arsenic)
≤0.5 ppm Pb (Lead)

density

1.15 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤5 ppm
phosphate (PO43-): ≤1 ppm
sulfate, sulfite (as SO42-): ≤5 ppm

cation traces

As: ≤0.05 ppm
Cu: ≤0.1 ppm
Fe: ≤1 ppm
heavy metals (as Pb): ≤0.5 ppm

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339261268003
grade

ACS reagent

grade

-

grade

reagent grade

assay

48%

assay

≥99.99% trace metals basis

assay

48%

Quality Level

200

Quality Level

200

Quality Level

200

form

liquid

form

liquid

form

liquid

vapor pressure

25 mmHg ( 20 °C)

vapor pressure

25 mmHg ( 20 °C)

vapor pressure

320 psi ( 21.1 °C), 8 mmHg ( 25 °C)

density

1.15 g/mL at 25 °C (lit.)

density

1.15 g/mL at 25 °C (lit.)

density

1.49 g/mL at 25 °C (lit.)

Application

Hydrofluoric acid solution can be used as a reagent to synthesize:
  • Cyanohydrin alkyl ethers via chiral Bronsted acid-mediated hydrocyanation of vinyl ethers with silyl cyanides.
  • N, N-Dimethylaniline hydrochloride salts via Pd-catalyzed Buchwald-Hartwig amination of aryl triflates with dimethylamines.
It can also be used as a catalyst for the amidation of carboxylic acids with amines to synthesize amides.

General description

Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. It is composed of hydrogen and fluoride. Hydrofluoric acid is a colorless and highly corrosive liquid. It is commonly used in the manufacture of hydrocarbons and polishing and conditioning glass. Additionally, it is used as a catalyst and in the synthesis of fluoride-containing compounds, and semiconductors. [1] [2]

pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1A

Lagerklasse

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable


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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. Does the 500 ml bottle come with a top cap with a spout?

    1 answer
    1. This product is packaged in an HDPE bottle with a polypropylene screw cap. The cap has a PTFE liner. A pouring spout or ring in not included.

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  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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