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Merck

09143

Benzaldehyde

analytical standard

Synonyme(s) :

Huile essentielle artificielle d’amandes

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A propos de cet article

Formule linéaire :
C6H5CHO
Numéro CAS:
100-52-7
Poids moléculaire :
106.12
NACRES:
NA.24
PubChem Substance ID:
329748697
eCl@ss:
39023701
UNSPSC Code:
41116107
EC Number:
202-860-4
MDL number:
MFCD00003299
Beilstein/REAXYS Number:
471223

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Nom du produit

Benzaldehyde, analytical standard

InChI key

HUMNYLRZRPPJDN-UHFFFAOYSA-N

InChI

1S/C7H6O/c8-6-7-4-2-1-3-5-7/h1-6H

SMILES string

O=Cc1ccccc1

grade

analytical standard

vapor density

3.7 (vs air)

vapor pressure

4 mmHg ( 45 °C)

assay

≥99.5% (GC)

form

liquid

autoignition temp.

374 °F

shelf life

limited shelf life, expiry date on the label

expl. lim.

1.4 %, 20 °F

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.545 (lit.)
n20/D 1.546

bp

178-179 °C (lit.)

mp

−26 °C (lit.)

density

1.044 g/cm3 at 20 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
flavors and fragrances
food and beverages
personal care

format

neat

Quality Level

100

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Cet article
PHR1203W212717W212709
Benzaldehyde analytical standard

Supelco

09143

Benzaldehyde

Benzaldehyde Pharmaceutical Secondary Standard; Certified Reference Material

Supelco

PHR1203

Benzaldehyde

Benzaldehyde natural, FCC, FG

Sigma-Aldrich

W212717

Benzaldehyde

Benzaldehyde ≥98%, FG, FCC

Sigma-Aldrich

W212709

Benzaldehyde

application(s)

cleaning products
cosmetics
environmental
flavors and fragrances
food and beverages
personal care

application(s)

cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care
pharmaceutical (small molecule)

application(s)

flavors and fragrances

application(s)

flavors and fragrances

grade

analytical standard

grade

certified reference material, pharmaceutical secondary standard

grade

FG, Fragrance grade, Halal, Kosher, natural

grade

FG, Halal, Kosher

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

-

technique(s)

-

format

neat

format

neat

format

-

format

-

assay

≥99.5% (GC)

assay

-

assay

≥98%

assay

≥98%

vapor density

3.7 (vs air)

vapor density

3.7 (vs air)

vapor density

3.7 (vs air)

vapor density

3.65 (vs air), 3.7 (vs air)

Application

Benzaldehyde may be used as a reference standard for the determination of benzaldehyde, the toxic oxidation product of benzyl alcohol used as a preservative in injectable formulations of the non-steroidal anti-inflammatory drugs, diclofenac, and piroxicam, and in vitamin B-complex injection solutions by capillary gas chromatography.[1]

General description

This substance is listed on the positive list of the EU regulation 10/2011 for plastics intended to come into contact with food.

Find all available reference materials for compounds listed in 10/2011 here

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Classe de stockage

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 1

flash_point_f

145.4 °F - closed cup

flash_point_c

63 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificats d'analyse (COA)

Lot/Batch Number
STBL4733
STBL1544
STBJ9754
STBH5776
STBH4561

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Capillary gas chromatography determination of benzaldehyde arising from benzyl alcohol used as preservative in injectable formulations.
Kazemifard AG, et al.
Journal of Pharmaceutical and Biomedical Analysis, 31(4), 685-691 (2003)
Micol Maritan et al.
Proceedings of the National Academy of Sciences of the United States of America, 106(9), 3537-3542 (2009-02-17)
A distinctive feature in the topographic organization of the olfactory system in mammals is the dual function of the odorant receptor (OR): it detects odors in the nasal epithelium and plays an instructive role in the axonal convergence of olfactory
Longyun Lv et al.
ACS combinatorial science, 15(4), 183-192 (2013-02-22)
We previously reported the novel efficient proton/heat-promoted four-component reactions (4CRs) of but-2-ynedioates, two same/different primary amines, and aldehydes for the synthesis of tetra- and pentasubstituted polyfunctional dihydropyrroles. If aromatic and aliphatic amines were used as reagents, four different series of
C Anitha et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 96, 493-500 (2012-06-26)
A series of metal(II) complexes of VO(II), Co(II), Ni(II), Cu(II) and Zn(II) have been synthesized from the azo Schiff base ligand 4-((E)-4-((E)-(4-chlorophenyl)diazenyl)-2-hydroxybenzylideneamino)-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one (CDHBAP) and characterized by elemental analysis, spectral (IR, UV-Vis, (1)H NMR, ESR and EI-mass), magnetic moment measurements, molar
Young Lok Choi et al.
Organic letters, 14(19), 5102-5105 (2012-09-19)
A one-pot transition-metal-free, base-mediated synthesis of dibenzo[b,f]oxepins was developed. The reaction of 2-halobenzaldehydes with (2-hydroxyphenyl)acetonitriles proceeds via a sequential aldol condensation and intramolecular ether formation reaction in the presence of Cs(2)CO(3) and molecular sieves in toluene.
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