If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
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About This Item
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Quality Level
assay
≥99%
form
solid
mp
250-254 °C (dec.) (lit.)
functional group
hydrazine
SMILES string
Cl[H].NNc1ccccc1
InChI
1S/C6H8N2.ClH/c7-8-6-4-2-1-3-5-6;/h1-5,8H,7H2;1H
InChI key
JOVOSQBPPZZESK-UHFFFAOYSA-N
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Related Categories
1 of 4
This Item | 127744 | 234435 | 159417 |
|---|---|---|---|
| assay ≥99% | assay 99% | assay 98% | assay 99% |
| solubility H2O: soluble 50 mg/mL | solubility H2O: soluble 50 mg/mL, clear, colorless, H2O: soluble, clear, colorless (50 mg/mL) | solubility - | solubility - |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| mp 250-254 °C (dec.) (lit.) | mp 227-230 °C (lit.) | mp 239-243 °C (dec.) (lit.) | mp 155-157 °C (dec.) (lit.) |
| form solid | form solid | form solid | form crystalline |
| functional group hydrazine | functional group amine | functional group - | functional group - |
Application
Biochem/physiol Actions
Preparation Note
Related product
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1
Storage Class
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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Can we store aliquots of PHZ (dissolved in PBS) in -20? How long does it remain stable? Thanks!
1 answer-
This product has not been evaluated for stability in solution. Phenylhydrazine HCl solutions may decompose when exposed to light and air. There are commercially available solutions in water that are packaged in amber glass and have an approximate shelf life of 1 year at room temperature, according to manufacturers. Note that this information has not been validated.
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Como puedo saber la fecha de caducidad si no aparece en el CoA?
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This product does not contain an expiration date or recommended retest date. Products with no expiration date or recommended retest date should be routinely inspected by customers to ensure they perform as expected. These products are also subject to a one year warranty from the date of shipment. For more information you may access the "Product Dating Information" document under "ADDITIONAL USEFUL DOCUMENTS ABOUT OUR PRODUCTS" at the bottom of the Quality Services page with this link: https://www.sigmaaldrich.com/life-science/quality-and-regulatory-management/quality-services.
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