528897

5-Bromo-2-iodotoluene

98%

• Linear Formula: CH₃C₆H₃(Br)I
• CAS Number: 116632-39-4
• Molecular Weight: 296.93
• NACRES: NA.22
• PubChem Substance ID: 24877624
• UNSPSC Code: 12352100
• MDL number: MFCD00060664

Properties

• Product Name: 5-Bromo-2-iodotoluene, 98%
• InChI: 1S/C7H6BrI/c1-5-4-6(8)2-3-7(5)9/h2-4H,1H3
• SMILES string: Cc1cc(Br)ccc1I
• InChI key: GHTUADBHTFHMNI-UHFFFAOYSA-N
• assay: 98%
• refractive index: n20/D 1.65 (lit.)
• bp: 263 °C (lit.)
• density: 2.08 g/mL at 25 °C (lit.)

Description

Application

5-Bromo-2-iodotoluene may be used in the synthesis of:

• 2-bromo-5-(4-bromo-2-methylphenyl)-3-methylpyridine[1]
• 4-bromo-4′-(carbazol-9-yl)-2-methylbiphenyl[2]
• 4,4′-dibromo-2-methyl-biphenyl[3]
• 3-methyl-4-phenylbromobenzene[4]
• 4-(4-bromo-2-methylphenyl)butanoic acid[5]

General description

5-Bromo-2-iodotoluene is a halogenated hydrocarbon. It undergoes chemoselective Suzuki reaction with phenylboronic acid to yield the corresponding carboxylic acid.[4]

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 10 - Combustible liquids
• wgk: WGK 3
• flash_point_f: 230.0 °F - closed cup
• flash_point_c: 110 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter