19-4150

Methyl salicylate

Name: Methyl salicylate
Brand: SAJ

SAJ first grade, ≥98.0%

Synonym(s):

2-Hydroxybenzoic acid methyl ester, Methyl 2-hydroxybenzoate, Oil of wintergreen, Wintergreen oil

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About This Item

Linear Formula:

2-(HO)C₆H₄CO₂CH₃

CAS Number:

119-36-8

Molecular Weight:

152.15

Beilstein/REAXYS Number:

971516

EC Number:

204-317-7

MDL number:

MFCD00002214

UNSPSC Code:

12352108

PubChem Substance ID:

329751868

Key Documents

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grade

SAJ first grade

vapor density

5.26 (vs air)

vapor pressure

1 mmHg ( 54 °C)

assay

≥98.0%

form

liquid

autoignition temp.

847 °F

availability

available only in Japan

refractive index

n20/D 1.536 (lit.)

bp

222 °C (lit.)

mp

−8-−7 °C (lit.)

density

1.174 g/mL at 25 °C (lit.)

SMILES string

COC(=O)c1ccccc1O

InChI

1S/C8H8O3/c1-11-8(10)6-4-2-3-5-7(6)9/h2-5,9H,1H3

InChI key

OSWPMRLSEDHDFF-UHFFFAOYSA-N

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Show Differences

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This Item	W274502	M6752	76631
Sigma-Aldrich 19-4150 Methyl salicylate	Sigma-Aldrich W274502 Methyl salicylate	Sigma-Aldrich M6752 Methyl salicylate	Supelco 76631 Methyl salicylate
grade SAJ first grade	grade FG, Fragrance grade, Halal, Kosher, natural	grade -	grade analytical standard
form liquid	form liquid	form liquid	form -
assay ≥98.0%	assay 98%	assay ≥99% (GC)	assay ≥99.0% (GC)
density 1.174 g/mL at 25 °C (lit.)	density 1.174 g/mL at 25 °C (lit.)	density 1.174 g/mL at 25 °C (lit.)	density 1.174 g/mL at 25 °C (lit.)
mp −8-−7 °C (lit.)	mp −8-−7 °C (lit.)	mp −8-−7 °C (lit.)	mp −8-−7 °C (lit.)
vapor density 5.26 (vs air)	vapor density 5.26 (vs air)	vapor density 5.26 (vs air)	vapor density 5.26 (vs air)

pictograms

GHS08,GHS05,GHS07

signalword

Danger

hcodes

H302,H317,H318,H361d,H412

pcodes

P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P308 + P313

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Repr. 2 - Skin Sens. 1B

Storage Class

10 - Combustible liquids

wgk_germany

WGK 2

flash_point_f

204.8 °F - closed cup

flash_point_c

96 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Solid phase extraction method for the separation and determination of chromium(III) in the presence of chromium(VI) using silica gel modified by N,N'-bis-(α-methylsalicylidene)-2,2-dimethyl-1,3-propanediimine.

Agata Bartyzel et al.

Analytica chimica acta, 707(1-2), 204-209 (2011-10-27)

N,N'-bis-(α-methylsalicylidene)-2,2-dimethyl-1,3-propanediimine (SBTD) modified silica gel was prepared and used as sorbent for solid phase extraction of Cr(III) ions from aqueous solution. This sorbent showed a high sorption affinity for Cr(III) while recovery of Cr(VI) was very low. The analyte ion

Complex odor from plants under attack: herbivore's enemies react to the whole, not its parts.

Michiel van Wijk et al.

PloS one, 6(7), e21742-e21742 (2011-07-19)

Insect herbivory induces plant odors that attract herbivores' natural enemies. Assuming this attraction emerges from individual compounds, genetic control over odor emission of crops may provide a rationale for manipulating the distribution of predators used for pest control. However, studies

Differential effects of plant ontogeny and damage type on phloem and foliage monoterpenes in jack pine (Pinus banksiana).

Nadir Erbilgin et al.

Tree physiology, 32(8), 946-957 (2012-06-05)

Coniferous trees have both constitutive and inducible defences that deter or kill herbivores and pathogens. We investigated constitutive and induced monoterpene responses of jack pine (Pinus banksiana Lamb.) to a number of damage types: a fungal associate of the mountain

UV-C-irradiated Arabidopsis and tobacco emit volatiles that trigger genomic instability in neighboring plants.

Youli Yao et al.

The Plant cell, 23(10), 3842-3852 (2011-10-27)

We have previously shown that local exposure of plants to stress results in a systemic increase in genome instability. Here, we show that UV-C-irradiated plants produce a volatile signal that triggers an increase in genome instability in neighboring nonirradiated Arabidopsis

Methyl salicylate-induced arginine catabolism is associated with up-regulation of polyamine and nitric oxide levels and improves chilling tolerance in cherry tomato fruit.

Xinhua Zhang et al.

Journal of agricultural and food chemistry, 59(17), 9351-9357 (2011-07-28)

The effects of methyl salicylate (MeSA) on chilling injury (CI) and gene expression levels, enzyme activities, and metabolites related to arginine catabolism in cherry tomato fruit were investigated. Freshly harvested fruits were treated with 0.05 mM MeSA vapor at 20

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