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223468

Sigma-Aldrich

Potassium permanganate

ACS reagent, ≥99.0%

Empirical Formula (Hill Notation):
KMnO4
CAS Number:
Molecular Weight:
158.03
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.21

grade

ACS reagent

Quality Level

assay

≥99.0%

form

crystals, granules or powder

reaction suitability

reagent type: oxidant

impurities

≤0.005% N compounds
≤0.2% insolubles

pH

7.2-9.7 (20 °C, 20 g/L)

anion traces

chloride, chlorate (as Cl-): ≤0.005%
sulfate (SO42-): ≤0.02%

SMILES string

[K+].[O-][Mn](=O)(=O)=O

InChI

1S/K.Mn.4O/q+1;;;;;-1

InChI key

VZJVWSHVAAUDKD-UHFFFAOYSA-N

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General description

Potassium permanganate (KMnO4) exhibits strong oxidizing properties. KMnO4 on dissolution in benzene and on complexation with dicyclohexyl-18-crown-6, affords a useful oxidizing reagent. This reagent participates as an oxidant for the oxidation of olefins, alcohols, aldehydes and alkyl benzenes under mild conditions.
Potassium permanganate, a dark violet colored crystalline solid, is a strong oxidizing agent for a wide range of organic compounds. It is commonly used as a disinfectant to treat external infections in aquaculture. Corncobs pretreated with alkaline potassium permanganate solution showed high carbohydrate recovery due to the increased enzymatic hydrolysis of lignocellulose. The acidic potassium permanganate acts a chemiluminescence reagent for the determination of organic compounds.

Application

Layered MnO2 with very promising characteristics for battery applications is produced by thermal decomposition of KMnO4.
Potassium permanganate may be employed as an oxidizing agent in the synthesis of the following:
  • sulfonal (2,2-bisethylsulfonyyl)propane
  • cinchomeronic acid (pyridine-3,4-dicarboxylic acid)
  • isonicotinic acid (pyridine-4-carboxylic acid)
  • manganese(IV) sulfate
Potassium permanganate may be used as an oxidant for the conversion of aromatic aldehydes to corresponding amides in liquid ammonia.
Suitable for heterogeneous oxidations.

Packaging

25, 500 g in poly bottle
2.5 kg in poly bottle

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 2 - Repr. 2 - Skin Corr. 1 - STOT RE 2 Inhalation

Target Organs

Brain

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

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Certificate of Origin

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