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338370
Pentamethylcyclopentadienylrhodium(III) chloride dimer
97%, solid
Synonym(s):
1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex, Bis(dichloro(pentamethylcyclopentadienyl)rhodium), Bis(pentamethylcyclopentadienylrhodium dichloride), Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer, Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
250 mg | Check Cart for Availability | $378.00 |
1 g | Check Cart for Availability | $938.00 $703.50 |
About This Item
Product Name
Pentamethylcyclopentadienylrhodium(III) chloride dimer, 97%
Quality Segment
assay
97%
form
solid
reaction suitability
core: rhodium, reaction type: C-H Activation, reagent type: catalyst
reaction type: C-Mannosylation
SMILES string
Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI
1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
InChI key
QNIVKTTWBMFSBR-UHFFFAOYSA-J
Application
Catalyst for:
- Oxidative olefination reactions
- C-C bond cleavage of secondary alcohols
- Ortho C-H olefination of phenol derivatives
- Oxidative annulation of pyridines
- Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond
- Amidation reactions
- Reductive alkylation reactions
- Oxidative olefination reactions
- C-C bond cleavage of secondary alcohols
- Ortho C-H olefination of phenol derivatives
- Oxidative annulation of pyridines
- Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond
- Amidation reactions
- Reductive alkylation reactions
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This Item | |||
|---|---|---|---|
| description 97% | description Umicore | description crystalline, ≥99.9% trace metals basis | description 99.95% trace metals basis |
| assay 97% | assay - | assay ≥99.9% trace metals basis | assay 99.95% trace metals basis |
| reaction suitability reaction type: C-H Activation, core: rhodium, reagent type: catalyst | reaction suitability reagent type: catalyst | reaction suitability reagent type: catalyst, core: rhodium | reaction suitability core: rhodium |
| form solid | form powder | form crystalline | form crystalline |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
Signal Word
Warning
Hazard Codes
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Skin Irrit. 2
Storage Class
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
dust mask type N95 (US), Eyeshields, Gloves
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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