453048
Dichlorobis(tri-o-tolylphosphine)palladium(II)
97%, solid
Sustainability features
Synonym(s):
PdCl2[P(o-Tol)3]2
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
1 g | Please contact Customer Service for Availability | $91.30 |
5 g | Please contact Customer Service for Availability | $288.00 $216.00 |
About This Item
Product Name
Dichlorobis(tri-o-tolylphosphine)palladium(II), 97%
Quality Segment
assay
97%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
core: palladium
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Sustainability features
mp
280 °C (dec.) (lit.)
SMILES string
Cl[Pd]Cl.Cc1ccccc1P(c2ccccc2C)c3ccccc3C.Cc4ccccc4P(c5ccccc5C)c6ccccc6C
InChI
1S/2C21H21P.2ClH.Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;;;/h2*4-15H,1-3H3;2*1H;/q;;;;+2/p-2
InChI key
OTYPIDNRISCWQY-UHFFFAOYSA-L
General description
Application
- Reaction of tributyltin enolates, prepared in situ from tributyltin methoxide and enol acetates, with aryl bromides.
- Coupling reaction of aryl bromides with vinylic acetates.
- Negishi-Reformatsky coupling reaction of aryl bromides with ethyl 2-(tributylstannyl)acetates.
- Synthesis of (E)-methyl 3-(7-indolyl)-2-methacrylate, via Heck reaction.
- Synthesis of imidazopyrimidine derivatives.
Catalyst for C-C and C-N coupling reaction.
1 of 1
This Item | |||
|---|---|---|---|
| description 97% | description 97% | description 95% | description 98% |
| reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Stille Coupling, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Cross Couplings, reagent type: catalyst | reaction suitability reaction type: Negishi Coupling, reagent type: catalyst, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, core: palladium, reaction type: Hiyama Coupling, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction | reaction suitability core: palladium, reaction type: Suzuki-Miyaura Coupling, reaction type: Stille Coupling, reaction type: Cross Couplings, reagent type: catalyst, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Hiyama Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction | reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Sonogashira Coupling, reagent type: catalyst, reaction type: Stille Coupling, core: palladium, reaction type: Negishi Coupling, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Heck Reaction |
| assay 97% | assay 97% | assay 95% | assay 98% |
| form solid | form solid | form solid | form solid |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 200 |
| mp 280 °C (dec.) (lit.) | mp 300-305 °C | mp 270 °C (dec.) (lit.) | mp - |
| sustainability Greener Alternative Product | sustainability - | sustainability Greener Alternative Product | sustainability - |
![trans-Dibromo[bis(tri-o-tolylphosphine)]palladium(II) 97%](/deepweb/assets/sigmaaldrich/product/structures/179/942/23421d20-ab3c-4203-9c26-0ab22b4bf263/640/23421d20-ab3c-4203-9c26-0ab22b4bf263.png)
Storage Class
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
Eyeshields, Gloves, type N95 (US)
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