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87741

Tetramethylammonium hydroxide pentahydrate

≥95.0% (T)

Synonym(s):

TMAH Pentahydrate

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25 g
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$83.70
100 g
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$198.00
500 g
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$560.00

About This Item

Linear Formula:
(CH3)4N(OH) · 5H2O
CAS Number:
Molecular Weight:
181.23
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-882-9
Beilstein/REAXYS Number:
3714235
MDL number:
Assay:
≥95.0% (T)
Form:
crystals

$83.70


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vapor density

1.1 (vs air)

Quality Segment

assay

≥95.0% (T)

form

crystals

autoignition temp.

878 °F

expl. lim.

36 %

reaction suitability

core: ammonium, reaction type: phase-transfer

impurities

≤0.1% halides (as chloride)

pH

(14 at ca.1,000 g/l at 20 °C (68 °F))

mp

67-70 °C (lit.)

solubility

soluble (2,200 g/l at 15 °C (59 °F))

anion traces

sulfate (SO42-): ≤1000 mg/kg

functional group

amine

SMILES string

O.O.O.O.O.[OH-].C[N+](C)(C)C

InChI

1S/C4H12N.6H2O/c1-5(2,3)4;;;;;;/h1-4H3;6*1H2/q+1;;;;;;/p-1

InChI key

MYXKPFMQWULLOH-UHFFFAOYSA-M

General description

Tetramethylammonium hydroxide pentahydrate is a clathrate hydrate, which shows high proton conductivity. It can readily uptake carbon dioxide. It is a promising candidate for energy devices, gas separation, and gas storage applications.

Application

Tetramethylammonium hydroxide pentahydrate is a clathrate hydrate, which shows high proton conductivity. It can readily uptake carbon dioxide. It is a promising candidate for energy devices, gas separation, and gas storage applications.

Tetramethylammonium hydroxide pentahydrate may be used in the preparation of a mesoporous molecular sieve belonging to the MCM-41 (mobil composition of matter No. 41) category with silica to (tetrahedral) aluminum ratio as low as 8.5:1.
Tetramethylammonium hydroxide pentahydrate is a clathrate hydrate, which shows high proton conductivity. It can readily uptake carbon dioxide. It is a promising candidate for energy devices, gas separation, and gas storage applications.

Disclaimer

material is sensitive vs air/moisture. filling, handling and storage under Argon!

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This Item
T7505331635426318
description

≥95.0% (T)

description

≥97%

description

25 wt. % in H2O

description

ACS reagent

assay

≥95.0% (T)

assay

≥97%

assay

-

assay

-

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

form

crystals

form

-

form

liquid

form

liquid

solubility

soluble (2,200 g/l at 15 °C (59 °F))

solubility

-

solubility

water: soluble

solubility

-

pH

(14 at ca.1,000 g/l at 20 °C (68 °F))

pH

-

pH

>13 (20 °C)

pH

-

vapor density

1.1 (vs air)

vapor density

1.1 (vs air)

vapor density

-

vapor density

-


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Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 1 Dermal - STOT SE 1

Target Organs

Central nervous system, Liver,thymus

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Regarding CAS.No.: 10424-65-4, please inform us the expiry/retest date as well as storage temperature.

    1 answer
    1. This product can be stored at room temperature.
      This product is not assigned an expiration date or recommended retest date. Customers should routinely inspect products with no expiration date or recommended retest date to ensure they perform as expected. These products are also subject to a one-year warranty from the date of shipment.

      For more information, you may access the "Product Dating Information" document under "ADDITIONAL USEFUL DOCUMENTS ABOUT OUR PRODUCTS" at the bottom of the Quality Services page with this link: https://www.sigmaaldrich.com/life-science/quality-and-regulatory-management/quality-services.

      Helpful?

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