If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
80457
Trifluoroacetic acid
eluent additive for LC-MS, LiChropur™, ≥99.0% (GC)
Synonym(s):
TFA
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About This Item
vapor density
3.9 (vs air)
Quality Segment
vapor pressure
97.5 mmHg ( 20 °C)
product line
LiChropur™
assay
≥99.0% (GC)
form
liquid
technique(s)
LC/MS: suitable
impurities
≤0.05% water, ≤50 mg/kg total sulfur (as SO4)
refractive index
n20/D 1.3 (lit.)
bp
72.4 °C (lit.)
mp
−15.4 °C (lit.)
solubility
water: soluble 10,000 g/L
density
1.489 g/mL at 20 °C (lit.)
anion traces
chloride (Cl-): ≤50 mg/kg, sulfite (SO32-): ≤10 mg/kg
cation traces
Ag: ≤0.05 mg/kg, Al: ≤0.1 mg/kg, Ba: ≤0.1 mg/kg, Bi: ≤0.5 mg/kg, Ca: ≤0.5 mg/kg, Cd: ≤0.1 mg/kg, Co: ≤0.05 mg/kg, Cr: ≤0.1 mg/kg, Cu: ≤0.05 mg/kg, Fe: ≤1.0 mg/kg, K: ≤1.0 mg/kg, Li: ≤0.1 mg/kg, Mg: ≤1.0 mg/kg, Mn: ≤0.1 mg/kg, Mo: ≤0.05 mg/kg, NH4+: ≤10 mg/kg, Na: ≤1.0 mg/kg, Ni: ≤0.1 mg/kg, Pb: ≤0.05 mg/kg, Sr: ≤0.05 mg/kg, Tl: ≤0.1 mg/kg, Zn: ≤0.1 mg/kg
SMILES string
OC(C(F)(F)F)=O
UV absorption
λ: 260 nm Amax: ≤0.9, λ: 270 nm Amax: ≤0.1, λ: 280 nm Amax: ≤0.08, λ: 290 nm Amax: ≤0.07, λ: 300 nm Amax: ≤0.06, λ: 320 nm Amax: ≤0.05
suitability
passes test for LC-MS
InChI
1S/C2HF3O2/c3-2(4,5)1(6)7/h(H,6,7)
InChI key
DTQVDTLACAAQTR-UHFFFAOYSA-N
General description
Features:
- Extensive QC testing ensures the highest specifications.
- Optimized to improve ionization and resolution.
- Extremely low levels of inorganic and organic impurities.
- Manufactured specifically for accurate and fast LC-MS.
Application
Packaging
Legal Information
1 of 1
This Item | |||
|---|---|---|---|
| assay ≥99.0% (GC) | assay ≥99.0% (GC) | assay 99% | assay ≥99.9% |
| Quality Level 100 | Quality Level 200 | Quality Level 200 | Quality Level 200 |
| form liquid | form liquid | form liquid | form liquid |
| solubility water: soluble 10,000 g/L | solubility water: soluble | solubility ethanol: soluble 0.33 mL/mL | solubility soluble 10 g/mL |
| density 1.489 g/mL at 20 °C (lit.) | density 1.489 g/mL at 20 °C (lit.) | density 1.489 g/mL at 20 °C (lit.) | density 1.489 g/mL at 20 °C (lit.) |
| anion traces chloride (Cl-): ≤50 mg/kg, sulfite (SO32-): ≤10 mg/kg | anion traces - | anion traces - | anion traces chloride (Cl-): ≤0.001%, fluoride (F-): ≤0.001%, sulfate (SO42-): ≤0.001% |
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1A
Storage Class
8B - Non-combustible corrosive hazardous materials
wgk
WGK 2
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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