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227676

Nickel(II) sulfate hexahydrate

ACS reagent, ≥98%

Nickel(II) sulfate hexahydrate
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100 g
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$42.70
500 g
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$187.00
2.5 kg
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$670.00

About This Item

Linear Formula:
NiSO4 · 6H2O
CAS Number:
Molecular Weight:
262.85
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-104-9
MDL number:
Assay:
≥98%
Grade:
ACS reagent
Form:
crystals

$42.70


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grade

ACS reagent

Quality Level

vapor density

2.07 (vs air)

assay

≥98%

form

crystals

reaction suitability

reagent type: catalyst
core: nickel

impurities

≤0.002% N compounds, ≤0.005% insolubles

anion traces

chloride (Cl-): ≤0.001%

cation traces

Ca: ≤0.005%, Co: ≤0.002%, Cu: ≤0.005%, Fe: ≤0.001%, K: ≤0.01%, Mg: ≤0.005%, Mn: ≤0.002%, Na: ≤0.05%

SMILES string

O.O.O.O.O.O.[Ni++].[O-]S([O-])(=O)=O

InChI

1S/Ni.H2O4S.6H2O/c;1-5(2,3)4;;;;;;/h;(H2,1,2,3,4);6*1H2/q+2;;;;;;;/p-2

InChI key

RRIWRJBSCGCBID-UHFFFAOYSA-L

General description

Nickel(II) sulfate hexahydrate is a hydrated nickel salt. It is used as a nickel precursor for the preparation of Ni-based catalysts.

Application

Nickel(II) sulfate hexahydrate (NiSO4 6H2O) can be used as a nickel precursor for the preparation of:     
  • Palladium-nickel bimetallic nanoparticles (Pd-Ni) which are used as a catalyst in the Buchwald-Hartwig amination reaction.
  • NiFe2O4 nanoparticles (NPs) applicable for the fabrication of a glucose biosensor.

It can also be used as a recyclable catalyst in:      
  • The synthesis of α-aminophosphonates via a one-pot three-component reaction of aromatic aldehydes, primary amines, and diethylphosphite.      
  • Trifluoromethylation of arylamine in the presence of Langlois′ reagent (CF3SO2Na) as CF3 source and potassium persulfate (K2S2O8) as initiator.


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This Item
9393314679011.06727
form

crystals

form

powder or crystals

form

solid

form

crystals

assay

≥98%

assay

≥99.9% trace metals basis, 98-102% (EDTA, complexometric)

assay

≥99.99% trace metals basis

assay

99.0-101.0% (complexometric)

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

300

grade

ACS reagent

grade

-

grade

-

grade

ACS reagent

anion traces

chloride (Cl-): ≤0.001%

anion traces

chloride (Cl-): ≤20 ppm

anion traces

chloride (Cl-): ≤0.001%

anion traces

chloride (Cl-): ≤0.001%

cation traces

Ca: ≤0.005%, Cu: ≤0.005%, K: ≤0.01%, Mn: ≤0.002%, Co: ≤0.002%, Mg: ≤0.005%, Fe: ≤0.001%, Na: ≤0.05%

cation traces

Al: <50 ppm, Ca: <50 ppm, Co: <50 ppm, Cu: <50 ppm, Fe: <50 ppm, K: <50 ppm, Mg: <50 ppm, Na: <50 ppm, Pb: <50 ppm, Zn: <50 ppm

cation traces

Ca: ≤0.005%, Co: ≤0.002%, Cu: ≤0.005%, Fe: ≤0.001%, K: ≤0.01%, Mg: ≤0.005%, Mn: ≤0.002%, Na: ≤0.05%

cation traces

Ca: ≤0.005%, Co: ≤0.002%, Cu: ≤0.002%, Fe: ≤0.001%, K: ≤0.01%, Mg: ≤0.005%, Mn: ≤0.002%, N: ≤0.001%, Na: ≤0.03%, Pb: ≤0.001%, Zn: ≤0.002%


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signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

target_organs

Respiratory Tract

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Articles

Experts discuss challenges and production processes of nickel-rich layered oxide cathode materials in energy storage systems.


Kun-Hua Lu et al.
Mikrochimica acta, 186(4), 227-227 (2019-03-09)
Water-soluble nitrogen-doped carbon quantum dots (C-dots) were fabricated by microwave-induced decomposition of the precursor materials citric acid and N,N'-bis(2-aminoethyl)-1,2-ethanediamine. The C-dots were placed on portable paper strips with novel origami designs to simplified user operations. The intensity of the blue
Polymorphism of nickel sulfate hexahydrate.
Angel RJ and Finger LW.
Acta Crystallographica Section C, Crystal Structure Communications, 44(11), 1869-1873 (1988)
Amperometric glucose biosensor based on NiFe2O4 nanoparticles and chitosan.
Luo L, et al.
Sensors and Actuators B, Chemical, 145(1), 293-298 (2010)



Global Trade Item Number

SKUGTIN
227676-2.5KG04061837768781
227676-500G04061837768798
227676-100G04061838780867

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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