Platinum Catalysts

We provide efficient platinum catalysts, e.g., platinum dioxide, also called Adams′ catalyst, used for the hydrogenation of various functional groups and dehydrogenation in organic synthesis. Platinum black, the active Pt catalyst, is formed during the reaction. Utilizing platinum catalysis on alkynes results in syn-addition, forming a cis-alkene. Two of the most important transformations using platinum catalysts include the hydrogenation of nitro compounds to amines and ketones to alcohols. Notably, reductions of alkenes can be performed with the Pt catalyst Adams′ catalyst in the presence of nitro groups without reducing the nitro group. Platinum catalysts are preferred over palladium catalysts to minimize hydrogenolysis when reducing nitro compounds to amines. This Pt catalyst is also used for the hydrogenolysis of phenyl phosphate esters, a reaction that does not occur with palladium catalysts.
Products

Chloroplatinic acid hexahydrate
ACS reagent, ≥37.50% Pt basis

Chloroplatinic acid solution
8 wt. % in H2O, liquid

Potassium hexachloroplatinate(IV)
reagent grade, 98%

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution
in xylene, Pt ~2 %

Platinum on carbon
extent of labeling: 10 wt. % loading, matrix activated carbon support, powder

Platinum(II) acetylacetonate
97%

Platinum(II) chloride
98%, powder

Platinum(IV) oxide
solid

Platinum on alumina
extent of labeling: 5 wt. % loading, powder

Platinum on graphitized carbon
extent of labeling: 20 wt. % loading

Platinum, nanoparticle dispersion
3 nm particle size, 1,000-1,300 ppm in H2O, 99.99% trace metals basis

Platinum on carbon
extent of labeling: 5 wt. % loading, matrix activated carbon support, powder

Platinum black
black, powder, ≤20 μm, ≥99.95% trace metals basis

Chloroplatinic acid hydrate
~38% Pt, powder

Platinum(IV) chloride
96%

Platinum(IV) oxide hydrate
≥99.9%

Tetraammineplatinum(II) nitrate
99.995% trace metals basis, solid

Potassium hexachloroplatinate(IV)
≥99.9% trace metals basis

Platinum(IV) oxide
solid

cis-Diamineplatinum(II) dichloride
≥99.9% trace metals basis
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