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Platinum Catalysts

Periodic Table Symbol for Platinum

We provide efficient platinum catalysts, e.g., platinum dioxide, also called Adams′ catalyst, used for the hydrogenation of various functional groups and dehydrogenation in organic synthesis. Platinum black, the active Pt catalyst, is formed during the reaction. Utilizing platinum catalysis on alkynes results in syn-addition, forming a cis-alkene. Two of the most important transformations using platinum catalysts include the hydrogenation of nitro compounds to amines and ketones to alcohols. Notably, reductions of alkenes can be performed with the Pt catalyst Adams′ catalyst in the presence of nitro groups without reducing the nitro group. Platinum catalysts are preferred over palladium catalysts to minimize hydrogenolysis when reducing nitro compounds to amines. This Pt catalyst is also used for the hydrogenolysis of phenyl phosphate esters, a reaction that does not occur with palladium catalysts.


Products

Sigma-Aldrich (26)
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Chloroplatinic acid hexahydrate
206083

Chloroplatinic acid hexahydrate

ACS reagent, ≥37.50% Pt basis

Chloroplatinic acid solution
262587

Chloroplatinic acid solution

8 wt. % in H2O, liquid

Potassium hexachloroplatinate(IV)
206067

Potassium hexachloroplatinate(IV)

reagent grade, 98%

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution
479519

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution

in xylene, Pt ~2 %

Platinum on carbon
205958

Platinum on carbon

extent of labeling: 10 wt. % loading, matrix activated carbon support, powder

Platinum(II) acetylacetonate
282782

Platinum(II) acetylacetonate

97%

Platinum(II) chloride
206091

Platinum(II) chloride

98%, powder

Platinum(IV) oxide
206032

Platinum(IV) oxide

solid

Platinum on alumina
205974

Platinum on alumina

extent of labeling: 5 wt. % loading, powder

Platinum on graphitized carbon
738549

Platinum on graphitized carbon

extent of labeling: 20 wt. % loading

Platinum, nanoparticle dispersion
773875

Platinum, nanoparticle dispersion

3 nm particle size, 1,000-1,300 ppm in H2O, 99.99% trace metals basis

Platinum on carbon
205931

Platinum on carbon

extent of labeling: 5 wt. % loading, matrix activated carbon support, powder

Platinum black
205915

Platinum black

black, powder, ≤20 μm, ≥99.95% trace metals basis

Chloroplatinic acid hydrate
81080

Chloroplatinic acid hydrate

~38% Pt, powder

Platinum(IV) chloride
206113

Platinum(IV) chloride

96%

Platinum(IV) oxide hydrate
520624

Platinum(IV) oxide hydrate

≥99.9%

Tetraammineplatinum(II) nitrate
482293

Tetraammineplatinum(II) nitrate

99.995% trace metals basis, solid

Potassium hexachloroplatinate(IV)
520861

Potassium hexachloroplatinate(IV)

≥99.9% trace metals basis

Platinum(IV) oxide
459925

Platinum(IV) oxide

solid

<I>cis</I>-Diamineplatinum(II) dichloride
479306

cis-Diamineplatinum(II) dichloride

≥99.9% trace metals basis

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