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499552

Sigma-Aldrich

Zinc preparation

5 g/dL Zn+2 in THF, highly reactive Rieke®metal

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Sinônimo(s):
Zn
Fórmula linear:
Zn
Número CAS:
7440-66-6
Peso molecular:
65.39
Número MDL:
MFCD00011291
Código UNSPSC:
12352300
ID de substância PubChem:
24873288
NACRES:
NA.22

Nível de qualidade

100

adequação da reação

core: zinc
reagent type: catalyst

concentração

5 g/dL Zn+2 in THF

densidade

0.949 g/mL at 25 °C

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

[Zn]

InChI

1S/Zn

chave InChI

HCHKCACWOHOZIP-UHFFFAOYSA-N

Categorias relacionadas

Aplicação

Rieke® Zinc metal can be used to reduce common organic functional groups such as aromatic nitro, conjugated aldehydes, arylacetylenes, and phenylpropiolates.

Informações legais

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Órgãos-alvo

Central nervous system, Respiratory system

Perigos de suplementos

EUH019

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

1.0 °F

Ponto de fulgor (°C)

-17.22 °C

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Rieke zinc as a reducing agent for common organic functional groups
Kroemer J, et al.
Tetrahedron Letters, 47(36), 6339-6341 (2006)
Casper Groth et al.
Development (Cambridge, England), 140(14), 3018-3027 (2013-06-21)
Developmental patterning requires the precise interplay of numerous intercellular signaling pathways to ensure that cells are properly specified during tissue formation and organogenesis. The spatiotemporal function of the Notch signaling pathway is strongly influenced by the biosynthesis and intracellular trafficking
I A Popov et al.
Molekuliarnaia biologiia, 47(3), 498-504 (2013-07-31)
Alzheimer's disease, is a lethal neurodegenerative pathology, characterized by the formation of soluble neurotoxic oligomers of the human amyloid-beta peptide Abeta which get accumulated forming polymeric extracellular aggregates (so-called amyloid plaques). The isomerized at aspartate 7 isoform of the human
A viewpoint about the treatment of Wilson's disease.
Abdul Qayyum Rana et al.
The Canadian journal of neurological sciences. Le journal canadien des sciences neurologiques, 40(4), 612-614 (2013-06-22)
M E Kuyumcu et al.
European review for medical and pharmacological sciences, 17(11), 1467-1471 (2013-06-19)
Zinc is one of the most important elements for human body. Zinc deficiency can occur in any age, if it is seen in elderly its clinical results can be more harmful due to already diminished functions. Some studies showed zinc
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Artigos

Rieke® Highly Reactive Metals

Metal-enhanced organic synthesis via organometallic intermediates is a widely used preparative route for thousands of organic compounds.

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