499552

Sigma-Aldrich

Zinc preparation

5 g/dL Zn+2 in THF, highly reactive Rieke®metal

Fórmula linear:
Zn
Número CAS:
Peso molecular:
65.39
Número MDL:
ID de substância PubChem:
NACRES:
NA.22

Nível de qualidade

100

reaction suitability

core: zinc
reagent type: catalyst

concentração

5 g/dL Zn+2 in THF

densidade

0.949 g/mL at 25 °C

temperatura de armazenamento

2-8°C

SMILES string

[Zn]

InChI

1S/Zn

InChI key

HCHKCACWOHOZIP-UHFFFAOYSA-N

Aplicação

Rieke® Zinc metal can be used to reduce common organic functional groups such as aromatic nitro, conjugated aldehydes, arylacetylenes, and phenylpropiolates.

Embalagem

100 mL in Sure/Seal™

Informações legais

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Palavra indicadora

Danger

hazcat

Acute Tox. 4 Oral - Aquatic Chronic 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2

Perigos de suplementos

EUH018 - EUH019

storage_class_code

3 - Flammable liquids

WGK Alemanha

WGK 2

Ponto de fulgor (ºF)

1.0 °F - closed cup

Ponto de fulgor (ºC)

-17.22 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificado de análise

Certificado de origem

Rieke zinc as a reducing agent for common organic functional groups
Kroemer J, et al.
Tetrahedron Letters, 47(36), 6339-6341 (2006)
A viewpoint about the treatment of Wilson's disease.
Abdul Qayyum Rana et al.
The Canadian journal of neurological sciences. Le journal canadien des sciences neurologiques, 40(4), 612-614 (2013-06-22)
Nalini Pandey et al.
Indian journal of experimental biology, 51(7), 548-555 (2013-08-01)
Black gram plants subjected to varying levels of Zn supply (0.01 to 10 microM Zn) showed optimum growth and dry matter yield in plants receiving 1 microM Zn. The dry matter yield of plants decreased in plants receiving 0.01 and...
M E Kuyumcu et al.
European review for medical and pharmacological sciences, 17(11), 1467-1471 (2013-06-19)
Zinc is one of the most important elements for human body. Zinc deficiency can occur in any age, if it is seen in elderly its clinical results can be more harmful due to already diminished functions. Some studies showed zinc...
W Reainthippayasakul et al.
Journal of nanoscience and nanotechnology, 13(5), 3617-3621 (2013-07-19)
Conjugated meso-alkynyl 5,15-dimesitylporphyrin metal complexes have been synthesized by Sonogashira coupling reaction in good yields. Alkynyl groups were chosen as a link at the meso positions in order to extend the pi-conjugated length of porphyrin rings. These synthesized porphyrin derivatives...
Artigos
Metal-enhanced organic synthesis via organometallic intermediates is a widely used preparative route for thousands of organic compounds.
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