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O7805

Oléylamine

technical grade, 70%

Synonyme(s) :

cis-1-Amino-9-octadécène, cis-1-Amino-9-octadécène

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A propos de cet article

Formule linéaire :
CH3(CH2)7CH=CH(CH2)7CH2NH2
Numéro CAS:
Poids moléculaire :
267.49
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
204-015-5
Beilstein/REAXYS Number:
1723960
MDL number:
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grade

technical grade

Quality Level

vapor pressure

8 mmHg ( 135 °C)

assay

70%

composition

primary amine, >98%

refractive index

n20/D 1.4596 (lit.)

bp

348-350 °C (lit.)

mp

18-26 °C (lit.)

density

0.813 g/mL at 25 °C (lit.)

SMILES string

[H]\C(CCCCCCCC)=C(/[H])CCCCCCCCN

InChI

1S/C18H37N/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19/h9-10H,2-8,11-19H2,1H3/b10-9-

InChI key

QGLWBTPVKHMVHM-KTKRTIGZSA-N

General description

L′oléylamine (OAm) est une alkyamine primaire à longue chaîne qui se comporte comme un donneur d′électrons à haute température. L′OAm présente une affinité pour les métaux grâce à ses groupements fonctionnels NH2. Des spectres FTIR de l′OAm ont été publiés. L′oléylamine sert d′agent fortement réducteur et de stabilisant dans la synthèse de nanoparticules.

Application

Produit utilisé dans la synthèse chimique et le coiffage de nanoparticules du type Fe3O4, copolymère greffé poly(2-hydroxyéthyl méthacrylate)-poly(ε-caprolactone), dioxyde de titane[1] ou silice mésoporeuse.[2]

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Cet article
909831HT-OA100369314
grade

technical grade

grade

-

grade

-

grade

technical grade

assay

70%

assay

-

assay

≥98% (primary amine)

assay

85%

density

0.813 g/mL at 25 °C (lit.)

density

0.813 g/mL at 25 °C (lit.)

density

0.813 g/mL at 25 °C (lit.)

density

0.849 g/mL at 25 °C (lit.)

mp

18-26 °C (lit.)

mp

18-26 °C (lit.)

mp

18-26 °C (lit.)

mp

0-5.0 °C (lit.)

refractive index

n20/D 1.4596 (lit.)

refractive index

n20/D 1.4596 (lit.)

refractive index

n20/D 1.4596 (lit.)

refractive index

n20/D 1.46 (lit.)

bp

348-350 °C (lit.)

bp

348-350 °C (lit.)

bp

348-350 °C (lit.)

bp

207 °C/13 mmHg (lit.)


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 - STOT SE 3

target_organs

Respiratory system

Classe de stockage

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

309.2 °F - closed cup

flash_point_c

154 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Certificats d'analyse (COA)

Lot/Batch Number

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Consulter la Bibliothèque de documents



Oleylamine in nanoparticle synthesis.
Mourdikoudis S and Liz-Marzan LM
Chemistry of Materials, 25(9), 1465-1476 (2013)
Monty Liong et al.
ACS nano, 2(5), 889-896 (2009-02-12)
Drug delivery, magnetic resonance and fluorescence imaging, magnetic manipulation, and cell targeting are simultaneously possible using a multifunctional mesoporous silica nanoparticle. Superparamagnetic iron oxide nanocrystals were encapsulated inside mesostructured silica spheres that were labeled with fluorescent dye molecules and coated
Oleylamine as both reducing agent and stabilizer in a facile synthesis of magnetite nanoparticles.
Xu Z, et al.
Chemistry of Materials, 21(9), 1778-1780 (2009)



Numéro d'article de commerce international

RéférenceGTIN
O7805-5G04061834248590
O7805-100G04061834248583
O7805-500G04061837835865

Questions

1–4 of 4 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. is it fine to store Oleylamine in plastic vials? Does it reacts with plastic or rubber cork present in the glass vials cap?

    1 answer
    1. This product is packaged in amber glass bottles and polypropylene screw caps with EPDM/PTFE liners. Compatibility testing with plastics and/or rubber corks has not been performed. Generally, plastic vials and rubber corks are chemically inert and often nonreactive with most chemicals. However, leaching or degradation cannot be ruled out. It is recommended that this material be stored in the original or similar containers to preserve the quality of the compound.

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  4. Is the O7805 Oleylamine technical grade 70% considered contaminated if the bottle arrived very cloudy?

    1 answer
    1. The material has a melting point between 18 °C and 26 °C, and it is normal for the product to become cloudy or precipitate in cold temperatures. The product is specified as a clear to hazy liquid, and gentle heating can be applied to restore its clarity

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