Skip to Content
MilliporeSigma

Key Documents

View All Documentation

Skip To

686271

(S)-4-Chloro-α-methylbenzyl alcohol

95%

Synonym(s):

(S)-1-(4-Chlorophenyl)ethanol, (S)-4′-Chloro-1-phenylethanol

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View
Pack SizeSKUAvailabilityPrice
1 g

Available to ship TODAYfromMILWAUKEE

$153.00

About This Item

Linear Formula:
ClC6H4CH(CH3)OH
CAS Number:
99528-42-4
Molecular Weight:
156.61
NACRES:
NA.22
PubChem Substance ID:
329761034
UNSPSC Code:
12352101
MDL number:
MFCD06797296
Assay:
95%
Form:
liquid

$153.00

Available to ship TODAYDetails

​
Request a Bulk Order
​
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Quality Level

100

assay

95%

form

liquid

optical activity

[α]20/D -48.0°, c = 1 in chloroform

refractive index

n20/D 1.544

density

1.175 g/mL at 25 °C

functional group

chloro, hydroxyl

SMILES string

C[C@H](O)c1ccc(Cl)cc1

InChI

1S/C8H9ClO/c1-6(10)7-2-4-8(9)5-3-7/h2-6,10H,1H3/t6-/m0/s1

InChI key

MVOSNPUNXINWAD-LURJTMIESA-N

Application

(S)-4-Chloro-α-methylbenzyl alcohol can be used as a chiral building block in:
  • The enantioselective synthesis of (-)-(S,S)-clemastine.[1]
  • The enantioselective and geometrically defined synthesis of chloro methylbenzyl pinacol boronic ester via lithiation−borylation methodology.

Compare Similar Items

View Full Comparison

Show Differences

1 of 1

This Item
686301686336323144
(S)-4-Chloro-α-methylbenzyl alcohol 95%

Sigma-Aldrich

686271

(S)-4-Chloro-α-methylbenzyl alcohol

(S)-4-Bromo-α-methylbenzyl alcohol 95%

Sigma-Aldrich

686301

(S)-4-Bromo-α-methylbenzyl alcohol

(R)-4-Bromo-α-methylbenzyl alcohol 95%

Sigma-Aldrich

686336

(R)-4-Bromo-α-methylbenzyl alcohol

(S)-(−)-α−Methyl-2-naphthalenemethanol 98%

Sigma-Aldrich

323144

(S)-(−)-α−Methyl-2-naphthalenemethanol

assay

95%

assay

95%

assay

95%

assay

98%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

form

liquid

form

liquid

form

liquid

form

-

density

1.175 g/mL at 25 °C

density

1.322 g/mL at 25 °C

density

1.322 g/mL at 25 °C

density

-

refractive index

n20/D 1.544

refractive index

n20/D 1.570

refractive index

n20/D 1.569

refractive index

-

functional group

chloro, hydroxyl

functional group

bromo, hydroxyl

functional group

bromo, hydroxyl

functional group

hydroxyl

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

>230.0 °F

flash_point_c

> 110 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKBN7473V
14917JH

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Stereospecific conversion of alcohols into pinacol boronic esters using lithiation-borylation methodology with pinacolborane
Roesner S, et al.
Chemical Communications (Cambridge, England), 50(31), 4053-4055 (2014)
Anne M Fournier et al.
Organic letters, 12(10), 2222-2225 (2010-04-22)
The first enantioselective synthesis of the antihistamine agent clemastine, as its (S,S)-stereoisomer, has been achieved by ether formation between a proline-derived chloroethylpyrrolidine and an enantiomerically enriched tertiary alcohol. The tertiary alcohol was formed from the carbamate derivative of alpha-methyl-p-chlorobenzyl alcohol

Global Trade Item Number

SKUGTIN
686271-1G04061826066935

Questions

Reviews

No rating value

Active Filters